1FLO: Perhalogenated Carba-closo-dodecaborate Anions as Ligand Substituents: Applications in Gold Catalysis
This 1FLO focuses on the fundamentals of catalysis and the interpretation of catalytic data. The questions guide students through the definition of catalysts, turnover frequency, turnover number, and require the students to extract information from a table of catalytic data. The data set comes from the unprecedented activity of carba-closo-dodecaborate ligated gold catalysts in hydroamination reported by Lavallo and coworkers in 2013 (Lavallo, V.; Wright II, J. H.; Tham, F. S.; Quinlivan, S. Angew. Chem. Int. Ed. 2013, 52, 3172.
Advanced Inorganic Chemistry
CHEM 405 Advanced Inorganic Chemistry – 4 Credit Hours
VIPEr Fellows 2022 Workshop Favorites
The second cohort of VIPEr fellows pulled together learning objects that they've used and liked or want to try the next time they teach their inorganic courses.
SLiThEr #36: CUREs in Chemistry
Kari Stone (Lewis University) and Kyle Grice (DePaul University) discuss the implementation of course-based undergraduate research experiences (CUREs) at their schools.
Bioinorganic Chemistry
Metals in biological systems can perform a wide range of reactions with exquisite efficiency and selectivity. In contrast, performing many of the same reactions in the lab requires harsh conditions and/or rare, expensive materials.
Inorganic Chemistry
The course will cover the elements of the periodic table that are omitted in general and organic chemistry, mainly the transition (d-block) metals.
Metal/Ligand Proton Tautomerism Facilitates Dinuclear H2 Reductive Elimination (Kuo)
This LO was developed in 2022 as part of a collection celebrating the “Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists” Inorganic Chemistry special issue. Check out the editorial and issue here: Editorial Special Issue
The questions below refer to the following 2020 publication by Dr. Jonathan Kuo and Dr. Karen Goldberg
Metal-Ligand Multiple Bonds: The Discovery of “Double Nickel” (Hillhouse)
This LO focuses on creating complexes with multiple bonds between late transition metals and nitrogen. The questions will guide students through Mindiola and Hillhouse's communication that details the synthesis and investigation of three-coordinate terminal amido and imido complexes of nickel. This communication is significant because it describes the synthesis and structural characterization of what became known as his "double nickel" complex, which contains a Ni-N double bond.
Substitution Chemistry in Odd-Electron Iron Group Carbonyl Complexes (D'Acchioli)
This LO brings together organometallic chemistry, electrochemistry, and computational chemistry in a complete whole, and shows how these different expertises and techniques all can add to our understanding of a rich chemical system. It might be of particular interest in a class dominated by even-electron and diamagnetic chemistry to give students an understanding of how practitioners approach odd-electron, paramagnetic systems.
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