In fall 2022, May Nyman from Oregon State was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in synthesis and development of polyoxometalates and metal oxohydroxoclusters, including their structures, speciation, reaction mechanisms, and function. In this literature discussion, students will examine her recent paper “Differentiating Zr/Hf Aqueous Polyoxocation Chemistry with Peroxide Ligation," Inorg. Chem. 2021, 60, 1631-1640 which is related to that work.

This Literature Discussion LO was created for the 2023 ACS Inorganic Chemistry Award Winners collection. Professor Shannon Stahl was the recipient of the 2023 Organometallic Chemistry Award. This LO is based on a recent paper from the Stahl group entitled "Can Donor Ligands Make Pd(OAc)2 a Stronger Oxidant? Access to Elusive Palladium(II) Reduction Potentials and Effects of Ancillary Ligands via Palladium(II)/Hydroquinone Reox Equilibria" published in J. Am. Chem. Soc. 2020, 142, 19678-19688.

This LO is in honor of the 2023 ACS Award in the Chemistry of Materials to Professor Reshef Tenne. Prof. Tenne was recognized for his contributions toward the development of inorganic fullerene-like nanoparticles and inorganic nanotubes.

This literature discussion LO was created for the ACS National Award Winners 2023 collection. Dr. Jerry Atwood was the recipient of the 2023 ACS Award in Inorganic Chemistry.

This Literature Discussion LO was created for the ACS Inorganic Chemistry Award Winners. Dr. Kit Cummins was the recipient of the 2023 Frederick Hawthorne Award in Main Group Inorganic Chemistry. This LO is based on a recent paper from the group of Dr. Cummins, entitled "Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite", published in ACS Central Science, 2022, 8, 332-339.

This paper describes the use of a  catalytic nickel system for the hydrodefluorination of aryl amides. While organofluorine compounds are extremely useful because of their unique properties, there are growing concerns about the impact of these compounds on the environment. Carbon-fluorine bonds are extremely strong, and so getting them to react is a significant challenge for chemists.

This paper describes work from the Milstein group in which ruthenium catalysts with pincer ligands are used to depolymerize nylons by breaking the C-N bond and hydrogenating the resulting products to amines and alcohols. Waste plastic is a serious environmental concern that needs a solution. Organometallic chemists put significant effort into finding ways to convert monomers into polymers, and now we must figure out ways to do the reverse.