KINETICS - Computations vs. Experiment

Submitted by Teresa J Bixby / Lewis University on Sat, 03/25/2017 - 12:10
Description

<p>This activity has students use Spartan to build an energy diagram for an SN2 reaction as a function of bond length. The activation energy can then be used to determine the rate constant for the reaction. After a few intoductory questions to orient general chemistry students to the organic reaction (with a short class discussion), the instructions lead them step-by-step to build the energy diagram for CH&lt;sub&gt;3&lt;/sub&gt;Cl + Cl- --&gt; Cl- + CH&lt;sub&gt;3&lt;/sub&gt;Cl.

calistry calculators

Submitted by Adam Johnson / Harvey Mudd College on Wed, 01/18/2017 - 18:17
Description

I just stumbled on this site while refreshing myself on the use of Slater's rules for calculating Zeff for electrons. There are a variety of calculators on there including some for visualizing lattice planes and diffraction, equilibrium, pH and pKa, equation balancing, Born-Landé, radioactive decay, wavelengths, electronegativities, Curie Law, solution preparation crystal field stabilization energy, and more.

I checked and it calculated Zeff correctly but I can't vouch for the accuracy of any of the other calculators. 

Symbolize It All

Submitted by Fabiola BL / The Cooper Union for the Advancement of Science and Art on Wed, 07/27/2016 - 13:58
Description

This is an HTML program that helps you spell with symbols of chemical elements for anything you want. Just cut and paste the text, paragraph or list of names you would like to "symbolize" in the left field. The program automatically displays the words that could be spelled with chemical symbols in the right field. When a word has more than one possible spelling, all of the possible combinations are displayed on a single line.

Chemical Information Available on the Web

Submitted by Matthew Riehl / Minnesota State University, Mankato on Thu, 06/30/2016 - 22:21
Description

This exercise introduces students to many chemical resources found on the internet.  Rather than being geared for upper-division chemistry majors, much of the material introduced is appropriate for freshmen and sophomore level students (although more advanced students will also benefit from the exercise).  The “web guide” contains links to many search engines and resources with brief descriptions of each while the “web report” has a number of exercises that asks students to search for chemical information.  The assignment is self-guided; students are encouraged to choose topic of interest t

Close Packing Activity

Submitted by George Lisensky / Beloit College on Tue, 06/28/2016 - 11:47
Description

Many extended structures can be viewed as close-packed layers of large anions, with the smaller cations fitting in between the anions. Larger holes between close-packed anions can hold cations with octahedral coordination. Smaller holes between close-packed anions can hold cations with tetrahedral coordination. The online jsmol resources show these layers and their holes.

Online Homework for a Foundations of Inorganic Chemistry Course

Submitted by Sabrina Sobel / Hofstra University on Mon, 06/27/2016 - 18:08
Description

The Committee on Professional Training (CPT) has restructured accreditation of Chemistry-related degrees, removing the old model of one year each of General, Analytical, Organic, and Physical Chemistry plus other relevant advanced classes as designed by the individual department. The new model (2008) requires one semester each in the five Foundation areas: Analytical, Inorganic, Organic, Biochemistry and Physical Chemistry, leaving General Chemistry as an option, with the development of advanced classes up to the individual departments.

Determining transition metal oxidation states: Recognizing bond metal-ligand types

Submitted by Brandon Quillian / Georgia Southern University on Mon, 06/27/2016 - 16:43
Description

In this in-class activity, students will determine the formal oxidation state of transition metal complexes by performing bonding type analysis of ligand−metal bonds. This in-class project is intended for those with little background in inorganic chemistry and aims to provide simple methods to calculate the formal charge of transition metals through bond-type analysis. While there are more sophisticated models already available to assign transition metal oxidation states, such as the LXZ (CBC) model, this exercise is intended for students who are coordination chemistry novices.

"Flipped Laboratory": A Discussion-based Electrochemistry Experiment for General Chemistry

Submitted by Samuel Esarey / University of Michigan on Mon, 06/27/2016 - 16:43
Description

This learning object is aimed at getting students to think critically about the data they collect in lab as they collect the data similar to how chemists typically conduct research.  They will be given a pre-lab video and a procedure prior to lab, conduct the experiment, and then upload their data to an Excel spreadsheet.  Students will then stay in their group to discuss the questions given to them on the worksheet in class with the instructor, and are allowed to continue working on them as a group up until the due date.

Will it Float? Density of a Bowling Ball Activity

Submitted by Terrie Salupo-Bryant / Manchester University on Mon, 06/27/2016 - 15:17
Description

This activity was adapted from the J. Chem. Ed. article, “Discrepant Event: The Great Bowling Ball Float-Off.” In this activity students use a bowling ball and some basic materials to predict whether the ball will sink or float in a tub of liquid. 

Solid State Stoichiometry Online

Submitted by George Lisensky / Beloit College on Mon, 06/27/2016 - 15:10
Description

The page has JSmol structures for unic cells including cubic, body centered cubic, and face centered cubic unit cells as well as for CsCl, Ni3Al, Cu2O, NaCl, CaF2, ZnS, diamond, Li3Bi, NaTl, NiAl and ReO3The advanced page also has triclinic, monoclinic, hexagonal, orthorhombic, and tetragonal cells with all possible centering.