Point group for H2O2 - why isn't it planar?

Submitted by Sophia E. Hayes / Washington University on Thu, 10/14/2010 - 10:57

This is the first time I've posted to a forum.  Hope "Research" was the right category.

 

I'm teaching a jr./sr. level Inorganic course using Miessler and Tarr.  I got a question from a student about hydrogen peroxide, H2O2 that I couldn't answer.  It's in  every textbook at  having C2 symmetry, but you'd expect (from a VSEPR picture) that it would be planar.  Apparently, it's not.  

 

Does anyone happen to know the reason why ... any good textbook discussion of this that you know of?

 

Thanks!

Sophia Hayes

Washington University

Forums

Circumstance finding of graphene wins this year's Nobel Prize in Physics

Submitted by AlanW / none on Mon, 10/11/2010 - 05:09

Graphene is ultra-thin, uncommonly powerful, and heat and electricity conduct through it with less resistance than any substance that exists. The discovery of graphene earned the $1.4 million 2010 Nobel Prize in Physics for two Russian physicists conducting analysis in England. Graphene's unique qualities have captivated scientists across the globe who are seeking quantum leaps in technology that can impact life on Earth in profound ways.

Graphene: Scotch tape found it

Forums

What computer programs do you use in your research?

Submitted by Kyle Grice / DePaul University on Wed, 07/28/2010 - 18:53

Hi there,

 I would like to start a thread on computer programs that people for research.  Please include what you use and why, and why you use it over any other options. Maybe people can learn about some options that are out there that they weren't aware of.  Lets see where this goes.

I'll start:

Forums

Need some molecules calculated?

Submitted by Lori Watson / Earlham College on Thu, 06/17/2010 - 08:23
Do you have some molecules you'd like to have some calculations on?  I've got three research students with me this summer who I know would love to help!  We mostly use density functional theory to calculate things like geometry, transition states, reaction energies, molecular orbitals, etc.  If you have an inorganic (no more than 2 metals) system (or even an organic one) you'd like calculated, let me know!
Forums
HELP Metal Migration???
We have samples that are Ni and Fe alloys electrodeposited on Au.  We have evidence to suggest that the metal deposit has migrated from the edges to the center over the course of a year.  Specifically the center is 1.7 times thicker than it used to be.  The diameter has decreased by 26% over the course of the year.  Does anyone have any insight or know anyone with insight with this phenomenon?
Nick / Hope College Fri, 06/11/2010 - 16:00
Forums

N,N-dimethyl-o-phenylenediamine

Submitted by Adam Johnson / Harvey Mudd College on Thu, 06/03/2010 - 18:49

or, o-N,N-dimethyl-aniline, or the dihydrochloride salt, or the sulfate, I don't care.

CAS: N,N-Dimethyl-o-phenylenediamine dihydrochloride, 62654-07-3

2-Amino-N,N-dimethylaniline    2836-03-5
N,N-Dimethyl-o-phenylenediamine    2836-03-5

I will buy you a Snickers bar if you happen to have this chemical in your stockroom and would be willing to send it to me.  This chemical used to be commerically available and I can not find it ANYWHERE anymore.  I would love 2-5 g.  Help?

Adam

Forums
Tags

NMR processing software

Submitted by Margaret Scheuermann / Western Washington University on Sun, 03/28/2010 - 00:17
This afternoon I came across a free version of the ACD Labs NMR processing software that I think was released fairly recently. It can be found here. Given how few free NMR programs there are, this seems like it could be a good option for undergraduate researchers or courses in which students will need to analyze significant amounts of NMR data outside of class time.
Forums

Most unusal NMR experiments?

Submitted by Hilary Eppley / DePauw University on Thu, 03/18/2010 - 13:16
This question is along the same lines as the "how many elements have you worked with" post below!   Last night some of the "pit VIPErs" (our pet name for those of us who got this site started) were discussing bizarre and interesting NMR experiments.  We thought it would be fun to compare the types of weird nuclei, pulse techniques, etc.  that the VIPEr users have done either in research or in a laboratory class.
Forums
Tags