HELP Metal Migration???

Submitted by Nick / Hope College on Fri, 06/11/2010 - 16:00
We have samples that are Ni and Fe alloys electrodeposited on Au.  We have evidence to suggest that the metal deposit has migrated from the edges to the center over the course of a year.  Specifically the center is 1.7 times thicker than it used to be.  The diameter has decreased by 26% over the course of the year.  Does anyone have any insight or know anyone with insight with this phenomenon?
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