National ACS Award Winners 2022 LO Collection
This collection of learning objects was created to celebrate the National ACS Award Winners 2022 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below.
SLiThErs - Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable
A collection of all of the IONiC VIPEr SLiThErs (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable). These events are short presentations on a topic followed by a period of discussion between the presenter and live participants. Each of these events is recorded and posted to the IONiC VIPEr YouTube Channel.
IONiC/VIPEr Survey
We are currently collecting data on the use of VIPEr materials in support of a future grant proposal. Please help keep this community functioning by taking a few minutes to respond. You can access the survey through this link. All answers are anonymous, but you have the option at the end of the survey to give us permission to quote you.
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Scandium Carbonyls - mysterious myth or legendary legend?
James F. Dunne / Central College
Thu, 03/06/2025 - 14:36
Description
This literature discussion is based on a short JACS communication reporting the first isolable Sc(II) carbonyls (not a typo) and isocyanides. The paper discusses some standard synthesis and characterization while exploring a more fundamental question regarding why Sc, a d-block metal, is considered a rare-earth and when it stops reacting analogously to the rare-earth metals. The LO focuses on ye olde carbonyl stretching frequencies and back-bonding and makes a nice follow up to an introduction to that concept. It tries to make students explicitly connect electron configuration to changes
Nickel-Catalyzed Enantioconvergent and Diastereoselective Allenylation of Alkyl Electrophiles: Simultaneous Control of Central and Axial Chirality (Greg C. Fu)
Description
This literature discussion LO was created for the ACS National Award Winners 2025 collection. Dr. Greg C. Fu for being the recipient of the Gabor A. Somorjai Award for Creative Research in Catalysis 2025 from the American Chemical Society.
Adducts of XeO3
Description
This literature discussion was prepared as part of the 2025 ACS awards collection in honor of Gary J. Schrobilgen, winner of the M. Frederick Hawthorne Award in Main Group Inorganic Chemistry.
AsF5 - a superacid for super review!
Description
This LO was developed as a review activity for the end of the semester. Students are required to touch on a wide range of topics including acid-base theories, crystal systems, point groups, the spectrochemical series, and 19F NMR spectroscopy. A close reading of the paper is required helping to build student comprehension of the literature.
Eight Coordinate Zirconium?
Description
This discussion is intended as a brief application of symmetry and ligand coordination to a novel Zr compound. Students apply VSEPR and molecular symmetry to an uncommon organometallic compound, and apply the coordination mode to basic reactivity. It is intended for an in-class activity but could easily be assigned as a short homework assignment.
Exploring the Electronegativity and Hardness of the Noble Gases
Description
This is a literature discussion focused on calculating and comparing the Mulliken electronegativites of the noble gases. Students can explore how this periodic property extends into the noble gases and impacts the observed reactivity of Group 18 compounds. The discussion could be used either as an in-class activity or a homework assignment.