National ACS Award Winners 2022 LO Collection

This collection of learning objects was created to celebrate the National ACS Award Winners 2022 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

Shirley Lin / United States Naval Academy Sat, 03/12/2022 - 07:01

IONiC/VIPEr Survey

We are currently collecting data on the use of VIPEr materials in support of a future grant proposal.  Please help keep this community functioning by taking a few minutes to respond. You can access the survey through this link.  All answers are anonymous, but you have the option at the end of the survey to give us permission to quote you.

If you are a registered VIPEr faculty user, you may have already taken this survey.  Thank you for your help!

Flavodiiron Oxygen Reductase

Submitted by Amanda Reig / Ursinus College on Thu, 11/20/2025 - 09:44
Description

This paper investigates factors that influence substrate specificity (O2 versus NO reductase activity) within flavodiiron enzymes. The authors mutate potentially relevant amino acids and investigate the biochemical and biophysical properties by UV-visible and EPR spectroscopies.

1FLO: Addition of H2 to four-coordinate iridium
Description

This paper (J. Organomet. Chem. 2022, 965-966, 122317) describes the synthesis and reactivity of four-coordinate iridium compound with a tridentate ligand. This ligand is referred to in the paper as a pincer ligand which are a general class of tridentate ligands that coordinate in a mer- arrangement.

Chip Nataro / Lafayette College Wed, 10/22/2025 - 13:41
Metallocene cations and anions
Description

This is a really interesting paper in J. Am. Chem. Soc. (2025, 147, 34641-34646) involving a complex salt in which both the cation and anion are metallocenes. While a majority of the paper is focused on the characterization of two new compounds, it presents some excellent opportunities to practice counting electrons, one of which was a challenge to this author.

Chip Nataro / Lafayette College Tue, 09/23/2025 - 11:39
Rhenium isocyanide complexes from the Figueroa group
Description

This literature discussion is in honor of Dr. Josh Figueroa, recipient of the 2026 F. Albert Cotton Award in Synthetic Inorganic Chemistry. Josh has done some tremendous work with isocyanide ligands and this paper is but a brief glimpse into this field. The complexes of interest contain carbonyl ligands and isocyanide ligands, so there are plenty of opportunities for students to use group theory to predict the number of IR-active vibrations for these ligands.

Chip Nataro / Lafayette College Tue, 08/26/2025 - 13:34