Fluorine Azide and Fluorine Nitrate: Structure and Bonding
Description
This literature discussion was written for a foundation-level inorganic chemistry course to accompany the material on Lewis structures. It utilizes a communication-length article on fluorine azide and fluorine nitrate. The assignment is divided into two parts: a set of questions for students to answer BEFORE they read the communication and then a set of questions that they answer after reading the article.
Synthesis and electronic properties of transition metal complexes containing sulfonamidoquinoline ligands a literature-based activity and discussion (Chan)
Description
This Learning Object is dedicated to Prof. Chan as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (June) 2022. A profile of Prof. Chan from the Chemical & Engineering News Out and Proud article can be found at
Analyzing the Proposed Reaction Profile in “Changing the Charge: Electrostatic Effects in Pd-Catalyzed Cross-Coupling”
Description
This LO is a literature discussion based on one figure in Chan et. al.
1FLO: Perhalogenated Carba-closo-dodecaborate Anions as Ligand Substituents: Applications in Gold Catalysis
Description
This 1FLO focuses on the fundamentals of catalysis and the interpretation of catalytic data. The questions guide students through the definition of catalysts, turnover frequency, turnover number, and require the students to extract information from a table of catalytic data. The data set comes from the unprecedented activity of carba-closo-dodecaborate ligated gold catalysts in hydroamination reported by Lavallo and coworkers in 2013 (Lavallo, V.; Wright II, J. H.; Tham, F. S.; Quinlivan, S. Angew. Chem. Int. Ed. 2013, 52, 3172.
Join us for SLiThEr #37 on June 22!
Please join us on Wednesday, June 22 at 4:00 pm Eastern for our 37th SLiThEr. Benny Chan (TCNJ) and Nancy Williams (Claremont Colleges) will lead a discussion on identity in the context of an inorganic chemistry course. We would love for you to come join the conversation!
Metal/Ligand Proton Tautomerism Facilitates Dinuclear H2 Reductive Elimination (Kuo)
Description
This LO was developed in 2022 as part of a collection celebrating the “Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists” Inorganic Chemistry special issue. Check out the editorial and issue here: Editorial Special Issue
The questions below refer to the following 2020 publication by Dr. Jonathan Kuo and Dr. Karen Goldberg
SLiTHEr #36 next week! CUREs in Chemistry June 9th, 4pm eastern
Dear Colleagues,
Metal-Ligand Multiple Bonds: The Discovery of “Double Nickel” (Hillhouse)
Description
This LO focuses on creating complexes with multiple bonds between late transition metals and nitrogen. The questions will guide students through Mindiola and Hillhouse's communication that details the synthesis and investigation of three-coordinate terminal amido and imido complexes of nickel. This communication is significant because it describes the synthesis and structural characterization of what became known as his "double nickel" complex, which contains a Ni-N double bond.