National ACS Award Winners 2022 LO Collection

This collection of learning objects was created to celebrate the National ACS Award Winners 2022 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

Shirley Lin / United States Naval Academy Sat, 03/12/2022 - 07:01
Literature Discussion Group Project
Description

This is a literature-based end of semester project.  After a semester of introducing literature in the form of typical literature discussions, this assignment is given to small groups.  It may be easily amended or added to.  Each group is provided with a paper and accompanying questions that are similar to the literature discussions they have done over the semester.  They then must use these guiding questions to assemble a presentation to the class.  The topics chosen and the guiding questions are designed to provide students with a taste of the many areas of inorganic chemistry that are no

Wes Farrell / United States Naval Academy Mon, 08/05/2024 - 14:23

Catalytic dechlorination of PVC

Submitted by Chip Nataro / Lafayette College on Wed, 07/24/2024 - 08:18
Description

This LO was inspired by a talk that Megan Fieser gave at the 2024 Organometallic Chemistry Gordon Research Conference. It was an excellent talk with some really interesting chemistry. Wanting something with practical application for my class focused on organometallic chemistry, I looked at one of her 'older' papers and found this really interesting rhodium catalyst. In the main paper for this LO (Mater. Horiz. 202310, 2047), the catalytic dechlorination of poly(vinyl chloride) (PVC) using a rhodium pincer complex is described.

Energetics of Formate Adsorption on Cu(111) by Calorimetry (Campbell)

Submitted by Nicole Crowder / University of Mary Washington on Fri, 03/15/2024 - 18:45
Description

This literature discussion LO was created for the ACS National Award Winners 2024 collection. Dr. Charles Campbell was the recipient of the 2024 Gabor A. Somorjai Award for Creative Research in Catalysis. This LO is based on the article "Energetics of Adsorbed Formate and Formic Acid on Cu(111) by Calorimetry,” (ACS Catal.

Visible Light-Absorbing Ruthenium Complexes: Choosing a Final Project in Inorganic Chemistry Laboratory from Two Real-World Applications

Submitted by Dr. Robert Perkins / Saint Louis University on Tue, 02/27/2024 - 11:13
Description

Laboratory Project Summary:

Students in an upper level Inorganic Chemistry lab course are given a choice between two final lab projects.  Both projects involve the synthesis of visible light-absorbing ruthenium complexes, however the subsequent application of these complexes correspond to different subfields within inorganic chemistry.  This feature allows them to pursue a project that continues to develop their synthetic, data-analysis, and writing skills while pursuing one that most closely aligns with their interests.

Pre-Equilibria Reaction Mechanism as a Strategy to Enhance Rate and Lower Overpotential in Electrocatalysis (Berben)
Description

This literature Discussion LO was created for the 2024 ACS Inorganic Chemistry Award Winners Collection.  Professor Louise A.

Rachel E. Siegel / University of California, Davis Mon, 02/26/2024 - 13:40

SLiThEr #57: What to do when your published results are questioned?

Submitted by Kyle Grice / DePaul University on Tue, 02/13/2024 - 15:19
Description

This was the 57th SLiThEr, presented by Dr. George Stanley, retired professor from LSU. It was a very interesting story and would be a valuable lesson to students about proper characterization and working with challenging and paramagnetic systems. 

Iridium dihydroxybipyridine complexes for hydrodeoxygenation
Description

I regularly give an oral exam instead of a written exam in my junior and senior level organometallics seminar course. The course focuses on the primary literature, discussion of advanced topics, and asking questions. A written exam would not evaluate the students' abilities on the important skill development they learned in the class. Besides, I am better able to gauge when a student has no idea about a certain topic, or just needs a little nudge in order for them to demonstrate that they actually understand 95% of it.

Adam Johnson / Harvey Mudd College Thu, 01/04/2024 - 17:50

Synthesis of Ti complexes supported by an ortho-terphenoxide

Submitted by Adam Johnson / Harvey Mudd College on Thu, 01/04/2024 - 16:21
Description

The Tonks group has helped to revitalize interest in early metal, especially titanium, organometallic chemistry in recent years. Often his group uses Ti complexes for multi-component coupling, increasingly with masked low-valent Ti(II) as an important intermediate. This paper is more fundamental, exploring a ligand based on ortho-terphenoxide since the meta- and para- derivatives were already known. Along the way, they report some interesting NMR and structural information, and finish with some hydroamination catalysis.