Foundations of Inorganic Chemistry for New Faculty
What is a foundations inorganic course? Here is a great description
What is a foundations inorganic course? Here is a great description
The application of physio-chemical principles to understanding structure and reactivity in main group and transition elements. Valence Bond, Crystal Field, VSEPR, and LCAO-MO will be applied to describe the bonding in coordination compounds. Organometallic and bio-inorganic chemistry will be treated, as will boranes, cluster and ring systems, and inorganic polymers. The laboratory will involve both synthetic and analytic techniques and interpretation of results.
VIPEr to the rescue!
The first year as a faculty member is extremely stressful and getting through each class day to day is a challenge. This collection was developed with new faculty teaching general chemistry in mind pulling together resources on the VIPEr site to refer back to as the semester drags along. There are some nice in-class activities, lab experiments, literature discussions, and problem sets for use in the general chemistry course. There are also some nice videos and graphics that could be used to spark interest in your students.
An overview of descriptive main group chemistry, solid state structures and the energetics of ionic, metallic, and covalent solids, acid-base chemistry and the coordination chemistry of the transition metals. The course is intended to explore and describe the role of inorganic chemistry in other natural sciences with an emphasis on the biological and geological sciences. Important compounds and reactions in industrial chemistry are also covered. Intended for both chemistry and non-chemistry majors.
This is a literature discussion based on a 2018 Inorganic Chemistry paper from the Lehnert group titled “Mechanism of N–N Bond Formation by Transition Metal–Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases“(DOI: 10.1021/acs.inorgchem.7b02333).
The activity is designed to be a literature discussion based on Nicolai Lehnert's Inorganic Chemistry paper, Mechanism of N-N Bond Formation by Transition Metal-Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases. The discussion questions are designed for an advanced level inorganic course.
The associated paper by Lehnert et al. uses DFT to investigate the reaction mechanism whereby a flavodiiron nitric oxide reductase mimic reduces two NO molecules to N2O. While being a rather long and technical paper, it does include several figures that highlight the reaction profile of the 4-step reaction. This LO is designed to help students learn how to recognize and interpret such diagrams, based on free energy in this case. Furthermore, using a simple form of the Arrhenius equation (eq.
This acitivty is a foundation level discussion of the Nicolai Lehnert paper, "Mechanism of N-N Bond Formation by Transition Metal-Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases". Its focus lies in discussing MO theory as it relates to Lewis structures, as well as an analysis of the strucutre of a literature paper.
Inorganic chemists often use IR spectroscopy to evaluate bond order of ligands, and as a means of determining the electronic properties of metal fragments.
This is a nanochemistry lab I developed for my Junior and Senior level Inorganic Chemistry course. I am NOT a nano/matertials person, but I know how important nanochemistry is and I wanted to make something where students could get an interesting introduction to the area. The first time I ran this lab was also the first time I made gold nanoparticles ever!
We do not have any surface/nano instrumentation here (AFM, SEM/TEM, DLS, etc... we can access them at other universities off-campus but that takes time and scheduling), so that was a key limitation in making this lab.