Inorganic Spectroscopy Introduced Using an Interactive PhET Simulation (Part 1)

Submitted by Alycia Palmer / The Ohio State University on Wed, 04/30/2014 - 20:49
Description

A guided-inquiry activity for the interactive PhET simuation "Molecules and Light" was created to introduce upper-level inorganic laboratory students to inorganic spectroscopy. The activity included here is the first part of a two-day discussion. This activity instructs students to use the PhET simulation "Molecules and Light" to explore how various molecules interact with different energies of electromagnetic radiation (microwave, infrared, visible, ultraviolet). This activity can also be used in a general chemistry setting as the topics discussed are very basic.

Symmetry Lectures

Submitted by Sabrina Sobel / Hofstra University on Sat, 03/08/2014 - 16:00
Description

Two excellent video presentations on symmetry. The Ted Talk by Marcus du Sautoy is an excellent introduction to the concept of symmetry and systematically describing it. In "Impossible Crystals" Nobel Laureate and physicist Paul Steinhardt discusses the creation of "Impossible crystals": quasi-crystals with five-fold symmetry previously believed impossible.

Electronic Absorption Spectroscopy of Aquated Transition Metal Ions

Submitted by Zachary Tonzetich / University of Texas at San Antonio on Thu, 01/23/2014 - 12:07
Description

I developed this laboratory experiment for our instrumental analysis class. The course is taken by junior and senior chemistry majors, who for the most part have had one inorganic chemistry course and some physical chemistry. The laboratory is operationally very simple and has students record the UV-vis spectra of transition metal sulfate salts in water using volumetric technique. They record the molar absorptivities for each peak and use this data to determine the number of waters of hydration for each salt by comparing with literature absorptivity values.

Five Slides about X-ray Photoelectron Spectroscopy (XPS)

Submitted by Sophia E. Hayes / Washington University on Fri, 06/28/2013 - 09:35
Description

This is a short presentation giving an overview of x-ray photoelectron spectroscopy (XPS), meant to be an introduction for those who are unfamiliar with the technique.

Molecular Structure - The Curious Case of Iron Tetracarbonyl

Submitted by Zachary Tonzetich / University of Texas at San Antonio on Thu, 06/27/2013 - 12:16
Description

This in-class activity traces the many contributions leading to the correct assignment for the solid-state structure of triiron dodecacarbonyl, [Fe3(CO)12],  with the aim of reinforcing ideas about IR spectroscopy and group theory. I give this activity to my advanced inorganic chemistry class (graduate students and senior undergrads). The activity is loosely based on the paper: Desiderato, R., Jr.; Dobson, G. R. J. Chem. Educ. 1982, 59, 752-756 and incorporates questions about symmetry and group theory for metal carbonyls.

Kool-Aid analysis: Visible Spectroscopy and Paper Chromatography

Submitted by Megan Strayer / The Pennsylvania State University on Wed, 06/26/2013 - 13:55
Description

This lab experiment is designed to introduce the electromagnetic spectrum to non-science majors in a food chemistry course by using everyday food (i.e. Kool-Aid packets). Students will use a spectrophotometer to correlate wavelength to color, as well as determine the mass percent of certain colored dyes in a Kool-Aid sample. Paper chromatography is also introduced to determine the number of dyes in a Kool-Aid sample. This lab is adapted from Sigmann, S; Wheeler, D. J. Chem. Ed., 2004, 81, p. 1475.

Databases for Kinetics

Submitted by Adam Johnson / Harvey Mudd College on Mon, 06/03/2013 - 15:02
Description

I recently came across some web resources for teaching kinetics. They are searchable compilations of kinetics data, principally gas-phase. Two of the sites include "recommended" data for use in simulations.

I describe the four sites here and the URLs are here and below.

http://jpldataeval.jpl.nasa.gov/
This is a critical tabulation of the latest kinetic and photochemical data for use by modelers in computer simulations of atmospheric chemistry

C(sp3)-F Activation through an Initial C(sp3)-H Activation Mechanism

Submitted by John Lee / University of Tennessee Chattanooga on Wed, 07/18/2012 - 16:35
Description

This paper is from a Science article from Alan Goldman’s group at Rutgers University. It was one of the literature articles that was assigned during the IONiC VIPEr Workshop in July 2012.  In conjunction with reading the article, workshop participants attended a seminar presented by Alan Goldman on this work.

Simple synthesis of MoO2(acac)2 and evaluation of spectra

Submitted by Patricia Stan / Taylor University on Mon, 07/16/2012 - 15:23
Description

A very simple lab synthesis that allows the student to carry out a coordination reaction and then look at the NMR and IR spectra.  I use this as a first lab to introduce them to using the NMR and IR.  If students work through the spectroscopy tutorial they should be able to explain the IR and NMR spectra.

NMR Coin-Flip Game

Submitted by azmanam / Butler University on Fri, 06/15/2012 - 09:19
Description

A simple coin-flipping game to help students understand the origin of spin/spin splitting in 1H NMR.