VIPEr Screencast
This screencast is a brief introduction to some of the features of VIPEr.
This screencast is a brief introduction to some of the features of VIPEr.
There are three ways to modulate the redox potential of a metalloenzyme: Changing ligands, changing geometry, and changing solvent. When I introduce this topic in Bioinorganic, I try to give my students concrete examples of each. I love this one because it applies what they learned in Gen Chem about the Nernst Equation to a biological problem. Granted, I don't use a metalloenzyme as my example, but I do pull the biological chemistry into it at the end, by referrring to the cytochrome oxidase/O2 couple.
This is a short presentation on cyclic voltammetry. It is covers the basics and some simple electrode mechanisms. There is room for improvement (especially in my art) and suggestions are welcome.
This is an in-class exercise to be used at the end of General Chemistry (II). I use it as a capstone exercise at the end of my second semester genchem course, but it would also make an excellent introductory review exercise at the beginning of a junior level inorganic course. It provides an excellent review of topics from the entire semester (electrochemistry, acid-base, thermodynamics, colligative properties, solution chemistry and calculations) and shows how they are inter-related in a real world application (a car battery).
When teaching reactions and mechanisms of inorganic complexes, I tend to get to the end of the chapter (out of breath) and find myself thinking "*$#&, I forgot about electron transfer". While I think it is important that students get an understanding of this in an upper level inorganic course, I simply don't have, or forgot to budget the time to really talk about it.
House (Inorganic chemistry): The book is divided into 5 parts: first, an introductory section on atomic structure, symmetry, and bonding; second, ionic bonding and solids; third, acids, bases and nonaqueous solvents; fourth, descriptive chemistry; and fifth, coordination chemistry. The first three sections are short, 2-4 chapters each, while the descriptive section (five chapters) and coordination chemistry section (seven chapters covering ligand field theory, spectroscopy, synthesis and reaction chemistry, organometallics, and bioinorganic chemistry.) are longer. Each chapter includes
Housecroft and Sharpe (Inorganic Chemistry, 3ed): This is a comprehensive inorganic textbook designed primarily for students at the Junior/Senior level. P-Chem would not be needed as a prerequisite for this text, but would be helpful. It includes both theoretical and descriptive material along with special topics, enough for a two semester course though it is easily adaptable to a one-semester "advanced inorganic" course by choosing only some topics. It is written in a clear and generally readable style and the full-color graphic contribute to student understanding.