This activity is meant to teach students about the types of homogeneous transition metal C-H bond functionalization catalysts. Before class, the students will read a short discussion of inner- and outer-sphere C-H bond functionalization catalysts. Then they will use their knowledge of transition metal oxidation states and ligands in order to assess whether a variety of catalysts react via inner- or outer-sphere pathways.

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This learning object is a literature discussion based on a paper published in Nature (Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507-514; doi:10.1038/446391a) discussing the mechanisms of C-H activation by transition metal complexes. This is a topic that could be covered at the end of a section on organometallic chemistry that shows a “newer” application.

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This is a simple and quick demonstration of the process oftempering of a solid, and the dramatic

Several years ago I began using a set of Ligand-of-the-Week exercises in my Inorganic course to encourage (force) students to go outside of our textbook and into the chemical reference materials and chemical literature to find examples of ligands that bind to metal ions. My motivation was to get my students to see the wonderful breadth of known metal-ligand complexes and to develop skills associated with analyzing and classifying ligands. My original paper is fairly complete and can be accessed via J. Chem. Educ. which is now available through the ACS website.

This is an in class activity to introduce the topic of multinuclear NMR, which is not covered (beyond ¹³C) in our sophomore level organic course. It is designed to walk the students through the process of predicting NMR spectra, as they learned in sophomore organic chemistry, but for a different I=1/2 nucleus, in this case ¹⁹F, which is I=1/2 and 100% abundant.