1FLO: Redox-switch polymerization catalysis

Submitted by Chip Nataro / Lafayette College on Fri, 03/22/2019 - 16:11
Description

This is what I hope will be a new classification of learning object called a one figure learning object (1FLO). The purpose is to take a single figure from a paper and present students with a series of questions related to interpreting the figure. This literature discussion is based on a paper (J. Am. Chem. Soc. 2011, 133, 9278) from Paula Diaconescu's lab in which a yttrium polymerization catalyst with a ferrocene-based ligand can effectively be rendered active or inactive depeneding on the valence state of the ligand.

Supramolecular Chemistry Videos

Submitted by Shirley Lin / United States Naval Academy on Sun, 03/03/2019 - 08:08
Description

The Rebek Laboratory homepage contains information on and molecular visualizations of a variety of host-guest systems developed by the research group over several decades. The theme behind this set of examples is the use of hydrogen-bonding to achieve self-assembly. Under the "Research" tab, one can find four videos with narration: an introduction to molecular assembly and three videos of specific examples of self-assembled host systems (the cavitand, the cylinder and the volleyball).

Inorganic Chemistry

Submitted by John Lee / University of Tennessee Chattanooga on Wed, 02/13/2019 - 14:25
Description

Catalog Description:  Concepts and models in inorganic chemistry with emphasis on atomic structure and bonding, molecular orbital theory, material science, and descriptive inorganic chemistry including biological and environmental applications.

More Electron Counting and CBC Assignments for Organometallic Complexes

Submitted by Matt Whited / Carleton College on Thu, 01/31/2019 - 14:55
Description

This in-class group activity extends my original post by providing more examples of varying difficulty for students to assign MLXZ classifications and electron counts to organometallic complexes.  The answers to these are unambiguous within the CBC system, but they provide excellent starting points for conversation with students about bonding formalisms with organometallics.

Guided Literature Discussion of “Next-Generation Water-Soluble Homogeneous Catalysts for Conversion of Glycerol to Lactic Acid”

Submitted by M. Watzky / University of Northern Colorado on Mon, 01/28/2019 - 14:50
Description

This Guided Literature Discussion was assigned as a course project, and is the result of work originated by students Joie Games and Benjamin Melzer.  It is based on the article “Next-Generation Water-Soluble Homogeneous Catalysts for Conversion of Glycerol to Lactic Acid” by Matthew Finn, J. August Ridenour, Jacob Heltzel, Christopher Cahill, and Adelina Voutchkova-Kostal in Organometallics 2018 37 (9), 1400-1409.

Inorganic Chemistry

Submitted by Kari Young / Centre College on Mon, 01/28/2019 - 11:23
Description

A study of the chemistry of inorganic compounds, including the principles of covalent and ionic bonding, symmetry, periodic properties, metallic bonding, acid-base theories, coordination chemistry, inorganic reaction mechanisms, and selected topics in descriptive inorganic chemistry. Laboratory work is required.

Guided Literature Discussion of “Mechanism of the Platinum(II)-Catalyzed Hydroamination of 4-Pentenylamines”

Submitted by M. Watzky / University of Northern Colorado on Wed, 01/16/2019 - 19:11
Description

This Guided Literature Discussion was assigned as a course project, and is the result of work originated by students Jana Forster and Kristofer Reiser.  It is based on the article “Mechanism of the Platinum(II)-Catalyzed Hydroamination of 4-Pentenylamines” by Christopher F. Bender, Timothy J. Brown, and Ross A. Widenhoefer in Organometallics 2016 35 (2), 113-125.

Advanced Inorganic Chemistry

Submitted by Darren Achey / Kutztown University on Tue, 09/11/2018 - 14:50
Description

The application of physio-chemical principles to understanding structure and reactivity in main group and transition elements. Valence Bond, Crystal Field, VSEPR, and LCAO-MO will be applied to describe the bonding in coordination compounds. Organometallic and bio-inorganic chemistry will be treated, as will boranes, cluster and ring systems, and inorganic polymers. The laboratory will involve both synthetic and analytic techniques and interpretation of results.

Descriptive Inorganic Chemistry

Submitted by RTMacaluso / University of Texas Arlington on Tue, 07/24/2018 - 14:26
Description

An overview of descriptive main group chemistry, solid state structures and the energetics of ionic, metallic, and covalent solids, acid-base chemistry and the coordination chemistry of the transition metals. The course is intended to explore and describe the role of inorganic chemistry in other natural sciences with an emphasis on the biological and geological sciences. Important compounds and reactions in industrial chemistry are also covered. Intended for both chemistry and non-chemistry majors.

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