The relevance of Transition Metal-Carbon Bonds in Biology and Chemistry

Submitted by Mwalimu / Russell Sage College on Tue, 07/15/2014 - 12:45
Description

The students will write a paper in which they analyze the Vitamin B12 co-enzyme from biological, chemical and biochemical perspectives, and will use the guided questions to help show the relevance of an organometallic chemistry experiment to real biochemical systems. This activity is based on a synthetic lab experiment that students would have performed on transition metal-carbon bonds in biology and chemistry (The lab experiment was adapted from third edition of “Inorganic Experiments” by Derek Woollins).

The Structure and Color of Alums

Submitted by EGunn / Simmons College on Mon, 07/14/2014 - 13:09
Description

This is an in-class assignment designed to help students integrate their understanding of periodic trends and materials properties. Using the color of alum crystals as an example of octahedral coordination chemistry, students use their knowledge of electronic structure and periodic trends to predict which of the isomorphous alum crystals will be colored, and to qualtitatively rank the degree of crystal field splitting in a family of alum crystals.

The Synthesis and Characterization of a trans-Dioxorhenium(V) Complex

Submitted by Sibrina Collins / College of Arts and Sciences at Lawrence Technological University on Mon, 07/14/2014 - 12:31
Description

This experiment involves the preparation of a key starting reactant in high purity and yield for an ongoing research project, specifically for the development of potential photodynamic therapy (PDT) agents. The students synthesize [ReO2(py)4]Cl.2H2O using standard inorganic synthesis techniques. The students visualize the vibrations and electronic properties (e.g. molecular orbitals) of the compound using output files generated from density functional theory (DFT).

Inorganic Spectroscopy Introduced Using an Interactive PhET Simulation (Part 2)

Submitted by Alycia Palmer / The Ohio State University on Mon, 07/14/2014 - 09:06
Description

This is the second part of a two-day class discussion on molecular and inorganic spectroscopy. In this activity, upper level students learn about spectroscopic tecniques used in inorganic chemistry and then devise an experiment to follow the progress of a hypothetical reaction. The activity also prepares students for the inorganic laboratory "Linkage isomerism of nitrogen dioxide" in which infrared spectroscopy is used to monitor changes to the N-O vibrational stretch upon coordination to a metal.

Coordination Diversity and Biological Activity of a Monodentate Au(III) Compound

Submitted by Sibrina Collins / College of Arts and Sciences at Lawrence Technological University on Thu, 07/10/2014 - 13:21
Description

 

This learning object focuses on a recent publication (Acta Crystallographia 2014, C70, 260 -266) by the Collins research group in the Department of Chemistry at The College of Wooster.  Specifically, the paper evaluates the coordination diversity of a N-donor ligand, 2-phenyl-1,10-phenanthroline(pnp) with three new pnp-metal complexes containing Au(III), Cu(II), and Pd(II) metal centers.

A Review of 3DMolSym: A Web Resource for Teaching Molecular Symmetry

Submitted by Marion Cass / Carleton College on Fri, 05/23/2014 - 19:22
Description

Introducing you to 3DMolSym:  A Web Resource for Teaching Molecular Symmetry that uses Adobe Shockwave for Visualizations and Animations.

Note there is a slight difference when operating this resource on a Mac or in a Windows Operating Systerm.  On a Mac if you don't change an item (any item) in the pull down menu on the right when the resouce opens, the selection of molecules will be frame shifted by one molecule.  An easy fix is described in the Description below.

The Structure and Symmetry of Metal Tris Chelates

Submitted by Marion Cass / Carleton College on Fri, 05/23/2014 - 15:59
Description

I have provided a link to a Web Resource:  The Strucutre and Symmetry of Metal Tris Chelates which I developed several years ago with my collegue Henry Rzepa from Imperial College London (and which was posted as Web Ware on the Jourmal of Chemical Education Website and is not longer available to view there).  The Web site uses 3D images of known molecules and scripted commands to teach about the symmetry elements and operations in these molecules.  Instruction is also given on assigning absolute configurations and ligand twist conformations.  Animations of the Bailar Twist and Ray Dutt Mech

Inorganic Spectroscopy Introduced Using an Interactive PhET Simulation (Part 1)

Submitted by Alycia Palmer / The Ohio State University on Wed, 04/30/2014 - 20:49
Description

A guided-inquiry activity for the interactive PhET simuation "Molecules and Light" was created to introduce upper-level inorganic laboratory students to inorganic spectroscopy. The activity included here is the first part of a two-day discussion. This activity instructs students to use the PhET simulation "Molecules and Light" to explore how various molecules interact with different energies of electromagnetic radiation (microwave, infrared, visible, ultraviolet). This activity can also be used in a general chemistry setting as the topics discussed are very basic.

Molecular Orbitals of Square-Planar Tetrahydrides

Submitted by Matt Whited / Carleton College on Fri, 04/18/2014 - 10:15
Description

This in-class activity walks students through the preparation of a molecular-orbital diagram for methane in a square-planar environment.  The students generate ligand-group orbitals (LGOs) for the set of 4 H(1s) orbitals and then interact these with carbon, ultimately finding that such a geometry is strongly disfavored because it does not maximize H/C bonding and leaves a lone pair on C.

'Sophomore' symmetry: Lecture materials

Submitted by Chip Nataro / Lafayette College on Thu, 03/27/2014 - 10:19
Description

Having been inspired by a number of wonderful LOs, I introduced group theory in my 'sophomore' inorganic class this spring. In addition to learning to determine the point group of a molecule, students were taught how to construct a qualitative MO diagram though the use of LGOs. While a little more than 5 slides, this is what I used in lecture to cover the material.