House: Inorganic Chemistry

Submitted by Adam Johnson / Harvey Mudd College on Mon, 01/12/2009 - 15:35
Description

House (Inorganic chemistry):  The book is divided into 5 parts:  first, an introductory section on atomic structure, symmetry, and bonding; second, ionic bonding and solids; third, acids, bases and nonaqueous solvents; fourth, descriptive chemistry; and fifth, coordination chemistry.  The first three sections are short, 2-4 chapters each, while the descriptive section (five chapters) and coordination chemistry section (seven chapters covering ligand field theory, spectroscopy, synthesis and reaction chemistry, organometallics, and bioinorganic chemistry.) are longer.  Each chapter includes

Electron Counting and a Catalytic Reaction

Submitted by Patrick Holland / Yale University on Mon, 07/28/2008 - 10:30
Description
This Challenge shows a catalytic process, and especially gives practice on electron-counting in transition metal complexes. Inorganic Challenges are exercises designed to be solved by a small group of students. Some Challenges practice a problem-solving algorithm, some reinforce important concepts, and some involve creativity or games.

Fluoro Analogue of Wilkinson's Catalyst

Submitted by Maggie Geselbracht / Reed College on Wed, 04/02/2008 - 01:24
Description
This paper describes the synthesis and characterization of the fluoro analogue of Wilkinson's catalyst [(Ph3P)3RhF]. The fluorine for chlorine switch causes an interesting change in the reactivity, promoting activation of C-Cl bonds in chloroarenes. Discussion of this paper nicely pairs with the chemistry of Wilkinson's catalyst, highlighting periodic trends in bonding and reactivity.

Miessler and Tarr: Inorganic Chemistry, 3rd. Ed

Submitted by Nancy Williams / Scripps College, Pitzer College, Claremont McKenna College on Fri, 03/28/2008 - 16:44
Description

Miessler and Tarr is an inorganic textbook which is is best suited to an upper-division one-semester inorganic course, though there is more material than can be covered in a single semester, so some choice of topics is necessary.  It is very well suited for a course oriented around structure, bonding, and reaction chemistry of transition metal compounds, but is very limited in its treatment of solids, main-group, descriptive chemistry, and bioinorganic.  Pchem would be helpful but is not necessary.  In particular, the treatment of MO theory is very in-depth.  The quality of end-of chapter p

Housecroft and Sharpe: Inorganic Chemistry, 3ed

Submitted by Lori Watson / Earlham College on Wed, 03/26/2008 - 20:01
Description

Housecroft and Sharpe (Inorganic Chemistry, 3ed): This is a comprehensive inorganic textbook designed primarily for students at the Junior/Senior level. P-Chem would not be needed as a prerequisite for this text, but would be helpful. It includes both theoretical and descriptive material along with special topics, enough for a two semester course though it is easily adaptable to a one-semester "advanced inorganic" course by choosing only some topics. It is written in a clear and generally readable style and the full-color graphic contribute to student understanding.

Literature Discussion: "Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds"

Submitted by Lori Watson / Earlham College on Sun, 03/09/2008 - 16:14
Description

This is a literature discussion assignment in which students read a paper, come up with their own answers to the provided questions (and submit them).  This is followed by a general in-class discussion on the paper.  This particular article deals with hydrosilyation of carbonyl compounds by a Re catalyst and describes the mechanism and kinetics in detail.  I found it a good paper to help students connect their P-chem (and inorganic) kinetics with a "real" system.  As part of the literature assignment, I also ask students to draw an MO diagram of a simple substrate (for review).