Metals in Biological Systems - Who? How? and Why?

Submitted by Betsy Jamieson / Smith College on Wed, 01/20/2010 - 10:01
Description

This learning object was developed collaboratively by members of the IONiC Leadership Council.  The overall goal is to provide a general overview of metals in biological systems and introduce students to several of the important ideas in the field of bioinorganic chemistry.  Topics include toxic metals, metals used in biological systems and the overlap of these categories; issues associated with the uptake, transport and storage of metal ions; and the benefits gained by using metals in biological molecules.  

Dinitrogen activation with "Side-on" N2 complexes

Submitted by Tarun Narayan / Harvey Mudd College on Wed, 12/16/2009 - 16:49
Description
This powerpoint presentation was created as part of the requirements for Chemistry 165 "Organometallics" at Harvey Mudd College during the fall semester 2009.  The authors of this presentation are Kristine Fong, Eric Nacsa and Tarun Narayan, all from Harvey Mudd College.  The activity consists of three items:  a powerpoint presentation, a script that goes along with the presentation, and a literature review (annotated bibliography) for further reading. 

Energy Nuggets: Wise Energy Use – The Challenge of Nitrogen Fixation

Submitted by Maggie Geselbracht / Reed College on Tue, 06/16/2009 - 01:33
Description
This literature discussion activity is one of a series of “Energy Nuggets,” small curricular units designed to illustrate: The Role of Inorganic Chemistry in the Global Challenge for Clean Energy Production, Storage, and Use.

IR Spectroscopy of Rhodium Carbonyl Clusters

Submitted by Maggie Geselbracht / Reed College on Tue, 04/07/2009 - 02:07
Description
The structures of neutral rhodium carbonyl clusters containing two, four, and six rhodium atoms have been known for some time.  In a recent paper (J. Am. Chem.

Inorganic Challenges

Submitted by Patrick Holland / Yale University on Tue, 03/10/2009 - 15:39
Description

The Interactive Inorganic Challenge Forum is a resource for inorganic chemistry teachers who want to incorporate team learning questions (“Challenges”) into an upper level undergraduate inorganic course. Through this site, teachers can exchange their ideas with others who have used inorganic chemistry Challenges. As a result, students benefit from field-tested group questions.

Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au+) Derived from a Triphosphine-Borane

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 15:21
Description
This is a guided set of questions for the paper: Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl,
AuCl, and Au+) Derived from a Triphosphine-Borane.  It was used to help students integrate the study of a variety of techniques (for example NMR, X-ray, computational studies) and basic organometallic chemistry into reading a "real" paper.

Using Computational Chemistry to discuss backbonding to CO

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 15:01
Description

This activity uses Gaussian with the WebMO interface to investigate the role of the metal in backbonding to CO as well as effects of the trans ligands. It can also be used as a way of introducing computational chemistry in an inorganic course.

House: Inorganic Chemistry

Submitted by Adam Johnson / Harvey Mudd College on Mon, 01/12/2009 - 15:35
Description

House (Inorganic chemistry):  The book is divided into 5 parts:  first, an introductory section on atomic structure, symmetry, and bonding; second, ionic bonding and solids; third, acids, bases and nonaqueous solvents; fourth, descriptive chemistry; and fifth, coordination chemistry.  The first three sections are short, 2-4 chapters each, while the descriptive section (five chapters) and coordination chemistry section (seven chapters covering ligand field theory, spectroscopy, synthesis and reaction chemistry, organometallics, and bioinorganic chemistry.) are longer.  Each chapter includes