The Extremely Explosive Carbonyl Diazide Molecule

Submitted by Maggie Geselbracht / Reed College on Sat, 03/19/2011 - 17:03
Description

This Lewis structure and VSEPR problem is based on a paper from Inorganic Chemistry in 2010 reporting the crystal structure of the carbonyl diazide molecule.  This relatively simple molecule provides an interesting application of the predictive powers of Lewis structures and VSEPR theory to molecular structure, backed up by experimental data on bond distances and bond angles.  Before tackling carbonyl diazide, the students warm up by considering the structures of hydrogen azide and the isolated azide ion.  The reference to the original paper is

hybrid orbitals for main group and transition metal complexes

Submitted by Adam Johnson / Harvey Mudd College on Tue, 03/08/2011 - 22:58
Description
This handout shows how the s, p and d orbitals of appropriate symmetry can mix in Cnv and Dnh point groups (n = 3-4). A high-level Gaussian calculation serves to "back up" my "back-of-the-envelope" drawings of some of the hybrid orbitals.

Metals and Life by Eleanor Crabb and Elaine Moore

Submitted by Amanda Reig / Ursinus College on Tue, 02/22/2011 - 08:27
Description

This appears to be an excellent introductory text for bioinorganic chemistry.  The authors assume no previous biochemistry knowledge and only a cursory understanding of concepts in inorganic chemistry is required.  Any student who has completed general chemistry should find most of the book readily accessible. 

Student Literature-Based Organometallic Lecture

Submitted by Jeffrey Rood / Elizabethtown College on Mon, 01/03/2011 - 14:42
Description
I taught an advanced inorganic chemistry course for the first time this past fall. I focused strictly on organometallic chemistry and we used Spessard and Miessler's book. Because this book is focused on transition metal organometallics, I wanted the students to appreciate some of the organometallic chemistry of the s- and p-block (and zinc). Students worked in pairs (the class size was 12) and had most of the semester to research the literature and develop a 40-50 minute lecture. I also had them develop homework questions and an in class activity to help engage the other students.

Synthesis and characterization of 12-tungstosilicic acid - a modification

Submitted by Randall Hicks / Wheaton College on Mon, 11/15/2010 - 23:25
Description
This lab experiment is an update on the synthesis of the title acid. An account of this synthesis can be found in William Jolly's book, The Synthesis and Characterization of Inorganic Compounds. The synthetic procedure is reliable and was retained. However, I modified some content and added components to extend to a two-week experiment. This lab now covers the synthesis, an acid-base titration with error analysis, and the use of TGA to complement the titration results.

The organometallic hypertext book

Submitted by Madeleine Schultz / Queensland University of Technology on Mon, 09/06/2010 - 06:11
Description

I am sure most people already use this but I always refer to students to the Organometallic hypertext book. It has excellent explanations of topics such as back-donation in organometallic complexes.

http://www.ilpi.com/organomet/

Dye-Sensitized Solar Cell 2010

Submitted by Simon Garcia / Kenyon College on Tue, 08/03/2010 - 16:37
Description

In this laboratory experiment, students construct a solar cell from a combination of synthetic and natural materials. It touches on a variety of chemical principles (kinetics, photochemistry, electrochemistry, intermolecular forces, material properties); however, the primary aim is the experience of turning materials into components and then assembling them into a working device. This experiment is unique in that it emphasizes each material's function, and how its properties affect this function. Students can seal these solar cells and take them home afterward.

The Berry Pseudorotation in PF5

Submitted by Maggie Geselbracht / Reed College on Sat, 03/20/2010 - 00:37
Description

This activity makes use of Jmol animations created by Prof. Marion Cass at Carleton College to illustrate the Berry Pseudorotation in trigonal bipyramidal molecules such as PF5.  Students explore the animations and answer a series of questions that lead to a description of this intramolecular motion that exchanges equatorial and axial atoms in trigonal bipyramidal molecules.  

Link to Jmol animations of Berry Pseudorotation

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