The set of questions in this literature discussion activity is intended to engage students in reading and interpreting scientific literature and to develop a clear and coherent understanding of agostic interactions.
This module offers students in an introductory chemistry or foundational inorganic course exposure to recent literature work.
This module offers students an introductory chemistry or foundational inorganic course exposure to recent literature work.
This paper describes the synthesis and characterization of a Cr(I) dimer with a very short Cr-Cr distance. Computational studies support fivefold bonding between the chromium atoms. This paper could be used to introduce metal-metal multiple bonds and discuss the molecular orbital interactions of homonuclear diatomics including d-orbitals. More generally, it is a nice example to stimulate the discussion of what constitutes a bond and the various interpretations of bond order.
This module offers students in an introductory chemistry or foundational inorganic course exposure to recent literature. Students will apply their knowledge of Lewis dot structure theory and basic thermodynamics to compare and contrast bonding in SiO2 and CO2.
This literature discussion is based on a paper describing the ligand-based reductive elimination of a diphosphine from a thorium compound (Organometallics, 2017, ASAP). The thorium compound contains two bidentate NHC ligands providing an opportunity to discuss the coordination of these ligands. The ligand-based reduction is very subtle and would be challenging for students to pick up without some guidance. The compound undergoing reductive elimination also presents an excellent introduction into magnetic nonequivalence and virtual coupling.
This problem set was designed to be an in-class activity for students to practice applying their knowledge of metal-metal bonding (as discussed in the previous lecture) to recently published complexes in the literature. In this activity, complexes from four papers by Christine M. Thomas and coworkers are examined to give students practice in electron counting (CBC method), drawing molecular orbitals, and fundamental organometallic reactions.
This is an in-class exercise developed based on a recent paper in Angewandte Chemie International Edition that reported a crystal structure of "six-coordinate" carbon. We normally think of carbon being four-coordinate at most, but this case has definitive evidence otherwise. However, we can use our inorganic chemistry knowledge to understand the structure and bonding of this molecule and rationalize its stability. Students do a pre-class exercise and then construct the MO of fhe molecule in class together.
This set of questions is intended to guide students through an excellent article by Jeff Byers and co-workers that describes the us
The literature discussion is based on a paper (Organometallics ASAP) in which the synthesis and reactivity of a palladium and platinum carbene compound. The palladium and platinum compounds exhibit some interesting differences that show up throughout the paper.