Metal/Ligand Proton Tautomerism Facilitates Dinuclear H2 Reductive Elimination (Kuo)

Submitted by Kyle Grice / DePaul University on Tue, 06/07/2022 - 11:11
Description

This LO was developed in 2022 as part of a collection celebrating the “Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists” Inorganic Chemistry special issue. Check out the editorial and issue here: Editorial  Special Issue

The questions below refer to the following 2020 publication by Dr. Jonathan Kuo and Dr. Karen Goldberg

Metal-Ligand Multiple Bonds: The Discovery of “Double Nickel” (Hillhouse)

Submitted by Anthony L. Fernandez / Merrimack College on Wed, 06/01/2022 - 00:52
Description

This LO focuses on creating complexes with multiple bonds between late transition metals and nitrogen. The questions will guide students through Mindiola and Hillhouse's communication that details the synthesis and investigation of three-coordinate terminal amido and imido complexes of nickel. This communication is significant because it describes the synthesis and structural characterization of what became known as his "double nickel" complex, which contains a Ni-N double bond.  

Discussion of "Dirhodium(II/II)/NiO Photocathode for Photoelectrocatalytic Hydrogen Evolution with Red Light" (Turro)

Submitted by Jason D'Acchioli / University of Wisconsin-Stevens Point on Sat, 05/21/2022 - 12:13
Description

This Learning Object is dedicated to Prof. Claudia Turro as part of the VIPEr LGBTQIAN+ LO collection created in celebration of Pride Month (Jun) 2022. Prof. Turro was featured in the April 2022 special virtual issue Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists (https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00729). Claudia holds a special place in my heart. I came out later in life, and she was incredibly supportive as I wrestled with my identity as a gay man.

Inorganic Chemistry

Submitted by Martin McPhail / University of West Georgia on Thu, 05/19/2022 - 15:19
Description

The wave nature of electrons is applied to atomic structure and periodic trends. Inter and intramolecular bonding models are used to interpret the chemical and physical properties of various materials, from simplistic diatomic molecules to structurally complex molecular and ionic systems.

Guess What: An Inorganic Chemistry Board Game

Submitted by Brad Wile / Ohio Northern University on Mon, 04/25/2022 - 17:46
Description

"Guess Who?" is a two player board game in which the object is to guess the identity of a character by asking questions about their appearance or features. This activity uses a similar game mechanic to identify concepts, models, and historical figures from inorganic chemistry. 

The ditungsten tetracarboxylate story (Sattelberger)

Submitted by Joanne Stewart / Hope College on Tue, 03/15/2022 - 09:37
Description

This literature discussion learning object examines the first reported synthesis in 1983 of the long anticipated quadruply bonded ditungsten tetracarboxylate dimers by Dr. Al Sattelberger and co-workers. This LO is part of a special VIPEr collection honoring the 2022 ACS National Award recipients in the field of inorganic chemistry. Alfred P. Sattelberger was the recipient of the 2022 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry.

Toward the Design of Phosphorescent Emitters of Cyclometalated Earth-Abundant Nickel(II) and Their Supramolecular Study (Yam)

Submitted by Kyle Grice / DePaul University on Tue, 03/08/2022 - 15:15
Description

This LO was created to celebrate Dr. Vivian W.-W. Yam's 2022 ACS Award, the Josef Michl Award in Photochemistry. These questions are written to help guide class discussion about this paper and the complexes in it. This LO would be good for an organometallics class or similar upper-division inorganic chemistry class. 

VIPEr nanoCHAt : NeWBiEs Spring 2022 Learning Objects

This collection accompanies the IONiC VIPEr nanoCHAt video series NeWBiEs, recorded in Spring 2022. This series is comprised of weekly conversations with two IONiC members, Wes Farrell and Shirley Lin from the US Naval Academy, as they taught a foundation-level inorganic chemistry course for the first time. The LOs discussed in the videos are included in this collection.

Shirley Lin / United States Naval Academy Wed, 02/02/2022 - 18:07