CHEM 4310 is an in-depth review of modern inorganic chemistry. Topics will include symmetry, acids and bases, reduction-oxidation reactions, periodic trends, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and material chemistry. The course will meet for three hours of lecture and three hours of laboratory per week.
Materials Chemistry will explore many of the fundamental relationships between a material’s chemical structure and the subsequent interesting and useful properties that result. In order for advances in electronic, magnetic, optical, and other niche applications to be made, an understanding of the structure-property relationship in these materials is crucial. This course will emphasize inorganic systems, and topics will include descriptions of various modern inorganic solid-s
This course will explore many of the fundamental principles of inorganic chemistry, with significant emphasis on group theory, molecular orbital theory, angular overlap theory, coordination chemistry, organometallic chemistry, and bio-inorganic chemistry. Specific topics will vary, but will generally include coverage of atomic structure, simple bonding theory, donor-acceptor chemistry, the crystalline solid state, coordination compounds and isomerism, electronic and infrared spectroscopy applied to inorganic complexes, substitution mechanisms, and catalysis.
In fall 2022, May Nyman from Oregon State was awarded the F. Albert Cotton Award in Synthetic Inorganic Chemistry for her outstanding accomplishments in synthesis and development of polyoxometalates and metal oxohydroxoclusters, including their structures, speciation, reaction mechanisms, and function. In this literature discussion, students will examine her recent paper “Differentiating Zr/Hf Aqueous Polyoxocation Chemistry with Peroxide Ligation," Inorg. Chem. 2021, 60, 1631-1640 which is related to that work.
This LO is submitted in honor of Alison Butler for her 2023 "ACS Award for Distinguished Service in Advancement of Inorganic Chemistry"
"For groundbreaking accomplishments in bioinorganic chemistry and leadership to the national and international chemistry community through the ACS Division of Inorganic Chemistry"
This Literature Discussion LO was created for the ACS Inorganic Chemistry Award Winners. Dr. Kit Cummins was the recipient of the 2023 Frederick Hawthorne Award in Main Group Inorganic Chemistry. This LO is based on a recent paper from the group of Dr. Cummins, entitled "Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite", published in ACS Central Science, 2022, 8, 332-339.
Chip Nataro (Lafayette College) hosts a live discussion covering the favorite labs that people teach. The discussion somewhat evolved into a conversation on "so, you are teaching inorganic lab for the first time...what do you do?"
This paper describes the use of a catalytic nickel system for the hydrodefluorination of aryl amides. While organofluorine compounds are extremely useful because of their unique properties, there are growing concerns about the impact of these compounds on the environment. Carbon-fluorine bonds are extremely strong, and so getting them to react is a significant challenge for chemists.
This paper describes work from the Milstein group in which ruthenium catalysts with pincer ligands are used to depolymerize nylons by breaking the C-N bond and hydrogenating the resulting products to amines and alcohols. Waste plastic is a serious environmental concern that needs a solution. Organometallic chemists put significant effort into finding ways to convert monomers into polymers, and now we must figure out ways to do the reverse.