Shilov Chemistry

Submitted by Allegra Liberman-Martin / UC Berkeley on Wed, 12/16/2009 - 16:29
Description
Description: 
This powerpoint presentation was created as part of the requirements for Chemistry 165 "Organometallics" at Harvey Mudd College during the fall semester 2009.  The authors of this presentation are Allegra Liberman-Martin (Scripps College), Levi Moore (Pomona College), Drexel Proctor (Pomona College) and Giselle Sullivan (Scripps College).  The activity consists of three items:  a powerpoint presentation, a script that goes a

Metal - Noble Gas Bonding

Submitted by Sisyphus / Harvey Mudd College on Tue, 12/15/2009 - 21:54
Description
This powerpoint presentation was created as part of the requirements for Chemistry 165 "Organometallics" at Harvey Mudd College during the fall semester 2009.  The authors of this presentation are Thomas Avila, Mark Hendricks, and Camille Sultana, all HMC students.  The activity consists of three items:  a powerpoint presentation, a script that goes along with the presentation, and a literature review (annotated bibliography) for further reading.  The presentation has links to figures;  the actual figures have been removed to prevent copyright violations.

Kevin Shaughnessy's Organometallic Chemistry Course

Submitted by Barbara Reisner / James Madison University on Wed, 10/28/2009 - 23:48
Description
On this website, Kevin Shaughnessy (of the University of Alabama) has very detailed lecture notes for his course in Organometallic Chemistry (CH609). He also posts problem sets and old exams and provides other resources for students enrolled in a course in organometallic chemistry.

Computational Organometallic Chemistry

Submitted by Tom Cundari / University of North Texas, Chemistry, CASCaM on Mon, 08/31/2009 - 17:57
Description
Lecture given at NSF-CENTC 2008 workshop on modeling in organometallic chemistry.

Catalytic cycles and artistry: Chalk Drawing 101

Submitted by Adam Johnson / Harvey Mudd College on Wed, 04/15/2009 - 14:19
Description

This is how I always end my organometallics unit in my advanced inorganic chemistry class.  The students have already learned electron counting, the major reaction types (oxidative addition (OA), reductive elimination (RE), 1,1- and 1,2-insertion, β­-hydrogen elimination, and [2+2] cycloadditi­ons), and have gone through naming elementary steps in class for some classic catalytic cycles (hydrogenation with Wilkinson's catalyst and the Monsanto acetic acid process).

IR Spectroscopy of Rhodium Carbonyl Clusters

Submitted by Maggie Geselbracht / Reed College on Tue, 04/07/2009 - 02:07
Description
The structures of neutral rhodium carbonyl clusters containing two, four, and six rhodium atoms have been known for some time.  In a recent paper (J. Am. Chem.

Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au+) Derived from a Triphosphine-Borane

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 15:21
Description
This is a guided set of questions for the paper: Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl,
AuCl, and Au+) Derived from a Triphosphine-Borane.  It was used to help students integrate the study of a variety of techniques (for example NMR, X-ray, computational studies) and basic organometallic chemistry into reading a "real" paper.

Using Computational Chemistry to discuss backbonding to CO

Submitted by Lori Watson / Earlham College on Sun, 03/08/2009 - 15:01
Description

This activity uses Gaussian with the WebMO interface to investigate the role of the metal in backbonding to CO as well as effects of the trans ligands. It can also be used as a way of introducing computational chemistry in an inorganic course.

Contemporary Inorganic Chemists

Submitted by Betsy Jamieson / Smith College on Tue, 01/13/2009 - 11:59
Description
This is an assignment I use to give students a sense of what kinds of problems real life, contemporary inorganic chemists work on.  I start out by having them find 2 contemporary inorganic chemists.  They give a 15-20 min presentation on their two chemists that gives a general overview of their research projects.  Once everyone has done their general presentation, I have students choose a specific journal article by one of their chemists to present in class.  I usually have this assignment run throughout the semester, with the general presentations taking place in the first half of the semeste

House: Inorganic Chemistry

Submitted by Adam Johnson / Harvey Mudd College on Mon, 01/12/2009 - 15:35
Description

House (Inorganic chemistry):  The book is divided into 5 parts:  first, an introductory section on atomic structure, symmetry, and bonding; second, ionic bonding and solids; third, acids, bases and nonaqueous solvents; fourth, descriptive chemistry; and fifth, coordination chemistry.  The first three sections are short, 2-4 chapters each, while the descriptive section (five chapters) and coordination chemistry section (seven chapters covering ligand field theory, spectroscopy, synthesis and reaction chemistry, organometallics, and bioinorganic chemistry.) are longer.  Each chapter includes