Submitted by Kurt Birdwhistell / Loyola University New Orleans on Sun, 02/01/2009 - 11:39
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Oral presentations in Inorganic chemistry- Ligand of the week

I have had students in the past give short oral Element reports.  They are given the following guidelines:
1.  Where is the element found in nature (biology or geology)?
    2.  How is the element used in society? As an element or in a Compound, etc.
    3.  Show some balanced equations involving the element making or breaking bonds.
    4.  Show structures of  compounds including the element.
    5.  Show chemistry you think is particularly interesting.

For some variety I am going to try the following exercise next fall.

I found the following exercise by Marion Cass, J. Chem. Educ.  2004, 81, (8), 1145; that I thought was a nice change from the typical element reports.  I am always looking for ways to put some variety into the course.  A little variety helps keep me interested.  

   Dr. Cass has different ligands of the week questions such as:
1.  Find ligands that bind through nitrogen, ligands that bind through oxygen, etc.
She/he has students answer several questions about each ligand and has the students give short oral presentations on their ligands.
    1.  give the name of the ligand and the name of a complex it forms with a metal
    2.  Draw lewis structure of the ligand and find hybridization of each atom in the ligand
    3.  Is it charged or neutral?
    4.  Is it chelating or monodentate?
    5.  Is there interesting chemistry associated with this ligand?  
She/he had several other possible questions  to add on.

Anyway I thought people on this list might be interested in this article.

 

Kurt

Maggie Geselbracht / Reed College

Kurt,

Wow!  I was just reading about this same Ligand of the Week exercise a few weeks ago and agree it looks like a fun idea to try.  

I came across Ligand of the Week on Marion Cass's website.  It looks like she has added a Jmol component to allow students to view the different ligands and the structural features of the typical complexes.  Click on the link on this page for Ligand of the Week Pages for 3-D Visualization.  This offers an interesting structural/crystallographic hook to the exercise.

If you do this in your class, I hope you'll post on your experiences!  Anybody else out there ever try something like this?

Cheers,
Maggie


Tue, 02/03/2009 - 01:09 Permalink
Kurt Birdwhistell / Loyola University New Orleans

In reply to by Maggie Geselbracht / Reed College

Hi Maggie,

I thought this "Ligand of the Week" exercise would be a nice one to combine with the Cambridge crystallographic database.  I have been seeking a way to incorporate the CCD into my class.  I will try it in the fall.

Kurt

Tue, 02/03/2009 - 15:57 Permalink
Hilary Eppley / DePauw University

In reply to by Kurt Birdwhistell / Loyola University New Orleans

Hi Kurt,

I've used the following as part of an "intro to chemical information exercise" but it could be easily adapted to a "ligand of the week" exercise: 

Choose a portion of the molecule (say 2 ligands and the metal or some other combination) and look it up using Cambridge Structural Database.  Indicate the fragment that you did a search on.  How many other compounds have been structurally characterized that also contain your chosen fragment?   How unique is the compound in the paper?

Cheers,

 Hilary

Thu, 02/05/2009 - 20:09 Permalink