The organometallic hypertext book
I am sure most people already use this but I always refer to students to the Organometallic hypertext book. It has excellent explanations of topics such as back-donation in organometallic complexes.
I am sure most people already use this but I always refer to students to the Organometallic hypertext book. It has excellent explanations of topics such as back-donation in organometallic complexes.
Early in 2009, Christopher Cummins’ group at MIT reported (in Science) the synthesis of AsP3, a compound that had never been isolated at room temperature. Later that year, a full article was published in JACS comparing the properties and reactivity of AsP3 to those of its molecular cousins, P4 and As4. The longer article is full of possibilities for discussion in inorganic chemistry courses, with topics including periodic trends, NMR, vibrational spectroscopy, electrochemistry, molecular orbital theory, and coordination chemistry.
Every time I teach inorganic, I always ask myself the question: “What’s the best way to motivate the course and get the students excited?” A long time ago, I decided it’s important to start with some music. (Until last year, Tom Lehrer’s The Elements was my favorite. As a TMBG fan, I’ve swiched to Meet the Elements.)
In the two years since this article was published, it has jump-started a large amount of research in the area of cobalt-based catalysts for solar water splitting. The paper describes the electrochemical synthesis and oxygen-evolution capabilities of a Co-phosphate catalyst under very mild conditions. The paper can stimulate discussion of many topics found in the inorganic curriculum, including electrochemistry, semiconductor chemistry, transition metal ion complex kinetic trends, and solid state and electrochemical characterization techniques.
This communication from the Journal of the American Chemical Society (J. Am. Chem. Soc.
This presentation provides a brief overview of the contributions of five AfricanAmerican chemists, including two inorganic chemists. George Washington Carver is quite often themost celebrated African American chemist (soil chemist), but he is only one individual! There are many other African Americans that have made important and significant contributions to the chemical sciences. The profiles include inorganic chemists, namely, Professor Gregory H. Robinson, University of Georgia and Dr. Novella Bridges, Pacific Northwest National Laboratory (PNNL).
Biological Inorganic Chemistry: Structure & Reactivity edited by Bertini, Gray, Stiefel, and Valentine was published by University Science Books (copyright 2007). It is a detailed text divided into 2 parts. Part A gives "Overviews of Biological Inorganic Chemistry" while Part B goes into more specifics of "Metal Ion Containing Biological Systems." Several prominent bioinorganic chemists have contributed chapters to the book in their various areas of expertise.