Geometric Control of C-C RE from a Pt(IV) Pincer Complex
When I saw this paper come out, I thought it would make a great teaching paper. It has synthesis, characterization, reaction mechanisms, computational chemistry and it directly impacts catalysis by a thorough examination of the reductive elimination reaction. What are the factors governing the rate of C-C RE? Can geometry (sterics) control reactivity or is it only based on the hybridization (sp2/sp3) of the carbon atom in question (electronics)?