2025 Nobel Prize in Chemistry - MOFs

Submitted by Chip Nataro / Lafayette College on Wed, 10/08/2025 - 08:43

In celebration of the 2025 Nobel prize in Chemistry awarded to Susumu Kitagawa, Richard Robson and Omar Yagi, this collection features various LOs about MOFs.

Metallocene cations and anions
Description

This is a really interesting paper in J. Am. Chem. Soc. (2025, 147, 34641-34646) involving a complex salt in which both the cation and anion are metallocenes. While a majority of the paper is focused on the characterization of two new compounds, it presents some excellent opportunities to practice counting electrons, one of which was a challenge to this author.

Chip Nataro / Lafayette College Tue, 09/23/2025 - 11:39
Rhenium isocyanide complexes from the Figueroa group
Description

This literature discussion is in honor of Dr. Josh Figueroa, recipient of the 2026 F. Albert Cotton Award in Synthetic Inorganic Chemistry. Josh has done some tremendous work with isocyanide ligands and this paper is but a brief glimpse into this field. The complexes of interest contain carbonyl ligands and isocyanide ligands, so there are plenty of opportunities for students to use group theory to predict the number of IR-active vibrations for these ligands.

Chip Nataro / Lafayette College Tue, 08/26/2025 - 13:34

SLiThEr #65: Publishing at a PUI

Submitted by Chip Nataro / Lafayette College on Mon, 07/28/2025 - 07:52
Description

Kyle Grice (DePaul) and Jacob Lutter (University of Southern Indiana) will present on how they have been successful in designing and publishing research at their respective PUI.

SLiThEr #64: Developing ACS Guidelines for Undergraduate Chemistry Programs

Submitted by Chip Nataro / Lafayette College on Mon, 07/28/2025 - 07:41
Description

A discussion about the 2023 ACS Guidelines for Undergraduate Chemistry Programs with Michelle Brooks (Assistant Director of the Office of Higher Education at ACS), Cora MacBeth (Emory University) and Barb Reisner (James Madison University). Additional discussion is available to registered faculty users.

SLiThEr #63: Catching up with Reilly and Sydney

Submitted by Chip Nataro / Lafayette College on Mon, 07/28/2025 - 07:25
Description

This goes back to SLiThEr #14 when we interviewed two senior undergraduates in the midst of the COVID pandemic. At the time of this SLiThEr, both are in graduate school and getting close to their PhD.

Reilly Gwinn (Virginia Tech) and Sydney Towell (UNC - Chapel Hill) update us on their career paths.

Hydrocyanation

Submitted by Chip Nataro / Lafayette College on Mon, 07/07/2025 - 07:35
Description

This literature discussion was inspired by a talk given by Dr. Nora Radu, recipient of the 2025 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry. It is a bit 'big picture' in nature in that the hydrocyanation reaction is important for the synthesis of nylon. As such, there is a significant amount of background material relating to nylon-6,6. Students will read an article from C&EN, portions of a patent, and portions of an article from J. Chem.

Interpreting Tanabe-Sunago diagrams

Submitted by Adam Johnson / Harvey Mudd College on Mon, 03/24/2025 - 17:27
Description

I was lecturing along today, teaching the basics of the theory and how to interpret Tanabe-Sunago diagrams, and I got to my slides where I show them how to calculate ∆o from Co(en)3, and it just fell apart. I had done V(III) as a first example, and then I wanted the students to practice the calculations, but my slides were not up to the task. I thought to myself, in the moment, this would be a good opportunity to do an in-class activity, I should write it. So, in the spirit of making next year easier, I did. I have not used this in class, but I wish I had had it this morning. 

3D Printed Crystal Structure Activity

Submitted by Chris Stromberg / Hood College on Wed, 03/19/2025 - 18:49
Description

This exercises uses beads to help show how different crystal structures are formed.  The exercise includes 3D-printed boxes with starting structures incorporated in the bottom to increase the stability of structures that students build.  The exercise also includes a number of additional 3D-printed manipulatives to help students visualize the unit cells and other properties of different crystal structures.  These include unit cells with accurate atomic and hold dimensions and several different ways to visualize the layer structures in close-packed structures.