This LO was developed in 2022 as part of a collection celebrating the “Out in Inorganic Chemistry: A Celebration of LGBTQIAPN+ Inorganic Chemists” Inorganic Chemistry special issue. Check out the editorial and issue here: Editorial  Special Issue

The questions below refer to the following 2020 publication by Dr. Jonathan Kuo and Dr. Karen Goldberg

This LO focuses on creating complexes with multiple bonds between late transition metals and nitrogen. The questions will guide students through Mindiola and Hillhouse's communication that details the synthesis and investigation of three-coordinate terminal amido and imido complexes of nickel. This communication is significant because it describes the synthesis and structural characterization of what became known as his "double nickel" complex, which contains a Ni-N double bond.  

This is a general assignment given prior to discussing a paper in class.  Students are asked to read a particular literature paper, and then fill out the template giving the citation information of the paper and: three (3) new things they learned from the paper, two (2) questions that reading the paper raised for them or left unanswered, and one (1) reference cited by the paper that the student thinks is worth reading and why.  The assignment helps seed the discussion prior to class, and gives the instructor some information about specific details to discuss to fill in gaps in the students'

This literature discussion focuses on a J. Am. Chem. Soc. communication that describes a series of Pt complexes that exhibit competitive reductive elimination reactions to form either an sp²-sp³ bond or an sp³-sp³ bond. One of the complexes also contains a C-C agostic interaction with the metal. The questions are written to be addressed by students in a foundation-level inorganic course.