This Literature Discussion is based on the article “Square-planar Co(III) {O4} coordination: large ZFS and reactivity with ROS” by Linda Doerrer et. al.
This paper in Science reports the synthesis of decamethyldizincocene, a stable compound of Zn(I) with a zinc-zinc bond. In the original LO, the title compound and the starting material, bis(pentamethylcyclopentadienyl)zinc, offer a nice link to metallocene chemistry, electron counting, and different modes of binding of cyclopentadienyl rings as well as more advanced discussions of MO diagrams.
This course is a survey of the chemistry of the inorganic elements focusing on the relationship between electronic structure, physical properties, and reactivity across the periodic table. Topics to be covered include: atomic structure, chemical bonding, group theory, spectroscopy, crystal field theory, coordination chemistry, organometallic chemistry and catalysis, and bioinorganic chemistry. Prerequisites: Successful completion of CH120, CH121, (with a C- or better) and CH 301 (suggested)
Course Description: An overview course covering the fundamental principles and theories of inorganic chemistry, with emphasis on the chemistry of d-block elements. Included topics are molecular structure, electronic structure and spectra, bonding descriptions and reaction mechanisms of coordination complexes along with an introduction to organometallic compounds of d-block elements and an introduction to molecular symmetry and point groups.
Structure and bonding in inorganic systems are the general subjects of this course. Both main group and transition metal chemistry are discussed.
This course covers fundamentals of central topics in inorganic chemistry from historical to modern-day perspectives. Topics include: coordination compounds (history, structure, bonding theories, reactivity, applications); solid state chemistry (crystals, lattices, radius ratio rule, defect structures, silicates & other minerals); and descriptive chemistry of the elements.
This course introduces the organometallic chemistry of the transition metals and main group elements with emphasis on common structural features and basic reaction types. The role of organometallic complexes in catalysis is also explored.
An introduction to modern inorganic chemistry, including a description of transition- metal complexes and their role as catalysts, and a survey of the reactivity of selected elements of the main group. Three-hour lecture, three-hour laboratory