This paper in Science reports the synthesis of decamethyldizincocene, a stable compound of Zn(I) with a zinc-zinc bond. In the original LO, the title compound and the starting material, bis(pentamethylcyclopentadienyl)zinc, offer a nice link to metallocene chemistry, electron counting, and different modes of binding of cyclopentadienyl rings as well as more advanced discussions of MO diagrams.
This course is a survey of the chemistry of the inorganic elements focusing on the relationship between electronic structure, physical properties, and reactivity across the periodic table. Topics to be covered include: atomic structure, chemical bonding, group theory, spectroscopy, crystal field theory, coordination chemistry, organometallic chemistry and catalysis, and bioinorganic chemistry. Prerequisites: Successful completion of CH120, CH121, (with a C- or better) and CH 301 (suggested)
Course Description: An overview course covering the fundamental principles and theories of inorganic chemistry, with emphasis on the chemistry of d-block elements. Included topics are molecular structure, electronic structure and spectra, bonding descriptions and reaction mechanisms of coordination complexes along with an introduction to organometallic compounds of d-block elements and an introduction to molecular symmetry and point groups.
Structure and bonding in inorganic systems are the general subjects of this course. Both main group and transition metal chemistry are discussed.
This course covers fundamentals of central topics in inorganic chemistry from historical to modern-day perspectives. Topics include: coordination compounds (history, structure, bonding theories, reactivity, applications); solid state chemistry (crystals, lattices, radius ratio rule, defect structures, silicates & other minerals); and descriptive chemistry of the elements.
This lecture course will introduce students to the interdependence of chemical bonding, spectroscopic characteristics, and reactivity properties of coordination compounds and complexes using the fundamental concept of symmetry. After reviewing atomic structure, the chemical bond, and molecular structure, the principles of coordination chemistry will be introduced. A basic familiarity with symmetry will be formalized by an introduction to the elements of symmetry and group theory. The students will use symmetry and group theory approaches to understand central atom hybridization, ligand
Four pairs of students represent quadruple bonding in metal complexes by "forming bonds" with a variety of physical methods involving actions like facing each other while holding hands (sigma bond), touch hands and feet of their partner "above and below" the plane (two pi bonds), touching hands and feet while facing each other (delta bond). This results in a "Twister"-like pile of students resembling the quadruple bonding interaction
This course introduces the chemistry of transition metals and main group elements. Topics include theories of bonding, kinetics and mechanisms of reactions of transition metal complexes, oxidation-reduction reactions, hard-soft acid-base theory, and solid-state chemistry. Applications of inorganic chemistry to other areas (organic, analytical, and physical chemistry, as well as biology and biochemistry) are highlighted throughout the course. The laboratory portion of the course involves the synthesis and spectroscopic investigation of inorganic complexes.
This course introduces the organometallic chemistry of the transition metals and main group elements with emphasis on common structural features and basic reaction types. The role of organometallic complexes in catalysis is also explored.