In this literature discussion, students read an Inorganic Chemistry paper (doi: 10.1021/ic503062w) about diarylamido-based PNZ pincer ligands and their Ni, Pd, and Rh complexes. Specifically, this paper uses IR and E1/2 potentials to demonstrate that the redox events occur not on the metal center but on the pincer ligands.
This is a powerpoint presentation that was developed for and used at the 2016 VIPEr workshop on Organometallic chemistry at the University of Michigan. Organometallic chemistry is a broad field, and we have divided ourselves into different classes based on what we study. For example, the reactivity of the third row metals is often quite different from that of the fourth/fifth rows. Early (high oxidation state with anionic ligands typically) and Late (low oxidation state with neutral ligands typically) metal complexes have different properties and d electron counts.
This assignment is intended to help students develop basic literature reading comprehension skills as well as connect the course content to relevant primary literature. Additionally the activity is coupled to short presentations that develop communication skills.
In the humanities it is common practice to read a piece of literature and discuss it. This is also practiced in science and is the purpose of this exercise. Each student is assigned a communication from the current literature (inorganic, JACS, organometallics, J. Phys.
Students are asked to choose a type of reaction from a set list (included), determine appropriate starting materials and the resulting product and present the reaction as though they accomplished it in the laboratory setting (5 min oral presentation with a 1 page paper). I asked the students to perform both a rough draft presentation (to me) and final draft presentation (to all students in laboratory).
This is an LO for the collection of organometallics LOs by George Stanley. Adam Johnson is curating the material that was written by George.
For many years, George hosted his organometallics lecture notes, powerpoint slides, and handouts, on his personal website at LSU. He always wanted that material available to the public. Recently, they moved to a CMS and that material is no longer available. Adam is working with George to get the 2016-2017 version of his materials up on VIPEr for everyone to use.
The lecture notes are freely available to all.
This literature discussion focuses on a paper from the Angelici lab that examines the heat of protonation of [CpʹIr(PR3)(CO)] compounds. The compounds presented in the paper provide good introductory examples for electron counting in organometallic compounds. The single carbonyl ligand in these compounds provide an excellent probe to monitor the electron richness at the metal center which is impacted by the electron donor ability of the ligands.
This list includes a number of LOs to help in teaching nanomaterials subjects; however, it is not exhaustive.
Updated June 2018.
Each spring semester I take on the task of teaching and grading full lab reports for my senior advanced inorganic chemistry class. For most this is their first experience writing a document of this magnitude as most other labs they have previously taken require either lab report sheets or the occasional abbreviated lab memo. As I read their lab reports each year I am reminded both how challenging it is to teach writing (more specifically scientific writing) and to grade the reports objectively.
In this experiment, students will synthesize and characterize a series of Ru(II) p-cymene piano-stool complexes.