This literature discussion was created during the 2023 IONiC VIPEr workshop at Morgan State University. It highlights the work of Prof. Robert J. Gilliard Jr.
This literature discussion on the Hot Paper communication in Chemistry, A European Journal; highlights the first examples of borepinium and borfluorenium cations whose optical properties can be tuned and also the very first reported example of thermochromism in these cationic species. R. J. Gilliard, Chem. Eur. J. 2019, 25, 12512. https://doi.org/10.1002/chem.201903348
This is a list of all of the learning objects developed in association with the 2023 content building workshop. Prof. Robert Gilliard was the featured speaker for this workshop, so most of the LOs will focus on his work.
This is a hands-on introduction to molecular symmetry and point groups. Students are not expected to have any exposure to molecular symmetry before this lab. Students work in pairs to identify symmetry elements in molecules and assign molecules to appropriate point groups.
In this activity, students will collectively build molecular orbitals for homonuclear diatomic molecules using balloons as models for atomic orbitals. This activity gets students up and moving and involved in the building of an MO diagram and allows for 3-D visualization of the core concepts of building molecular orbitals from atomic orbitals.
This literature discussion focuses on a 2022 Nature Comm paper looking at the reasons behind the pyramidal structures of tri-coordinate f-element complexes. There is plenty to discuss in terms of bonding and coordination geometries in metal complexes, and the effects of pressure on coordination geometry.
A guided inquiry activity for students to build the MO diagram for HF based on energetic and symmetry considerations. Students then compare their model to a standard MO diagram and examine what additional information a MO diagram conveys that the Lewis structure does not.
This Literature Discussion LO was created for the ACS Inorganic Chemistry Award Winners. Dr. Kit Cummins was the recipient of the 2023 Frederick Hawthorne Award in Main Group Inorganic Chemistry. This LO is based on a recent paper from the group of Dr. Cummins, entitled "Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite", published in ACS Central Science, 2022, 8, 332-339.
Chip Nataro (Lafayette College) hosts a live discussion covering the favorite labs that people teach. The discussion somewhat evolved into a conversation on "so, you are teaching inorganic lab for the first time...what do you do?"
This literature discussion is based on a 2022 Science paper describing a series of dilanthanide complexes with exceptional magnetic properties due to the presence of metal-metal bonding. These molecules are the first reported species to feature direct bonding between two lanthanides! The paper contains ample material for discussion of molecular symmetry and bonding, oxidation states and electron configurations, and magnetism. The handout includes a description, glossary, discussion questions, and pre-class worksheet.