Play-Doh Molecular Orbitals

Submitted by Sheri Lense / University of Wisconsin Oshkosh on Mon, 02/02/2015 - 13:56
Description

This is a simple activity designed to help students visualize the interaction of atomic orbitals to form molecular orbitals.  Students construct atomic orbitals out of Play-Doh and determine whether overlap of a given pairs of atomic orbitals along the specified axis can result in a σ, π, or δ interaction or no net interaction.  I do this activity following a reading assignment and lecture on the formation of molecular orbitals from atomic orbitals that cover the various types of interactions.  Students then work in groups of 3-4 to complete the instructions described on the attached worksh

Periodically Periodic

Submitted by Barbara Reisner / James Madison University on Sun, 01/25/2015 - 08:50
Description

I like having students look at data and then explain data based on what they know about periodic trends. This activity uses the data we all use for radii and ionization energies and asks students to look just a little bit deeper. 

I have gone back and forth between using this as an in class activity (my current practice) and using some of these questions on exams. 

Spacegroup visualizer

Submitted by Barbara Reisner / James Madison University on Mon, 01/19/2015 - 22:48
Description

This looks like a great resource to visualize the data contained in the international tables in 3D.

My colleague, John GIlje, recommended this resource to me. It's not something I'll use on a day to day basis because it requires a PC.

A Redox-Activated MRI Contrast Agent that Switches Between Paramagnetic and Diamagnetic States

Submitted by Vivian / Clemson University, Department of Chemistry on Wed, 07/16/2014 - 22:04
Description

Students are asked to read an article detailing the development of a cobalt-based MRI contrast agent ("A Redox-Activated MRI Contrast Agent that Switches Between Paramagnetic and Diamagnetic States", Tsitovich, P. B.; Spernyak, J. A.;  Morrow, J. R. Angew. Chem. Int. Ed. 201352, 14247-14250,  DOI: 10.1002/anie.201306394). Before coming to class the students are asked to answer a series of questions designed to guide them through the first half of the article, and to be prepared to discuss their answers in class.

Learning Objects used at the 2014 VIPEr Workshop on Bioinorganic Chemistry

Submitted by Betsy Jamieson / Smith College on Wed, 06/25/2014 - 09:32

This collection highlights the learning objects used at the 2014 VIPEr workshop on the Bioinorganic Applications of Coordination Chemistry to introduce participants to the field of bioinorganic chemistry.   They provide essential background information on how metals bind to proteins as well as the techniques used in the research papers presented at the workshop.  A list of learning objects created at the workshop based on the current research of our expert speakers can be found at: 

Exploring Proteins as Ligands using the Protein Data Bank

Submitted by Betsy Jamieson / Smith College on Tue, 06/17/2014 - 15:23
Description

This in class activity is designed to introduce students to how amino acid side chains can coordinate metal ions in proteins.  It guides students through the exploration of several metal binding sites in proteins using the Ligand Explorer program on the Protein Data Bank (PDB) website.  Essentially, it is a way for them to use the PDB to “discover” the information generally presented on this topic in the introductory chapters of bioinorganic textbooks.  At the end it asks students to think about Hard Soft Acid Base theory and to see how that can be applied to the binding of metals in protei

Coordination complexes and crystal field theory in-class worksheet

Submitted by Sarah K. St. Angelo / Dickinson College on Mon, 04/28/2014 - 18:39
Description

This is an in-class activity that I made to help students in my second semester general chemistry course work through some aspects of color and coordination chemistry.  The activity was performed with a demonstration of color for nickel coordination complexes (ligands: water, ethylenediamine, and ammonia). I also included equilibria and thermodynamics as those concepts apply to coordination compounds at the introductory level.  This served as a review of the concepts as well.

Molecular Orbital of Transition Metal Complexes

Submitted by Steven Neshyba / University of Puget Sound on Wed, 02/05/2014 - 21:39
Description

Students construct computer models of two transition metal complexes, solve their electronic structures, and inspect the resulting d-type molecular orbitals to identify which are non-bonding, sigma* antibonding, or pi* antibonding. After constructing a molecular orbital diagram, they determine which of the two complexes is likely to absorb light at a longer wavelength.

m&m Language

Submitted by Shirley Lin / United States Naval Academy on Fri, 09/13/2013 - 08:52
Description

This in-class activity is intended to help visualize the meaning of the subscripts and coefficients in molecular formulas that appear in balanced chemical equations. It has been my experience that students in 2nd semester general chemistry can sometimes still be confused about this fundamental aspect of chemical language. It substitutes edible candy for the atoms in a molecular model kit, thus allowing students to eat the atoms at the end. (My philosophy is that if students are eating, they're probably awake and could be learning!)

Introduction to Synchrotron Radiation

Submitted by Megan Strayer / The Pennsylvania State University on Thu, 06/27/2013 - 15:35
Description

This 5 slides about gives a basic introduction to synchrotron radiation.  Information includes how the particles are accelerated, how they travel to the individual instruments, and where synchrotrons in the USA are located.