Solid State Chemistry - A physics perspective
Description
I found this website really useful for explaining basic solid state concepts.
Computational Organometallic Chemistry
Description
Lecture given at NSF-CENTC 2008 workshop on modeling in organometallic chemistry.
Introduction to High Resolution Spectroscopy
Description
http://assign3.chem.usyd.edu.au/spectroscopy/index.php
A series of Java tools for learning about the relationship between molecular parameters (size, mass etc) and the form of the spectral trace. These cover rotational, vibrational, ro-vibrational and electronic spectroscopy.
Basics of Computational Chemistry
Description
I would use this VERY brief introduction to computational chemistry in my inorganic course to preface a computational based assignment. While one learning goal for such an assignment might be familiarity with WebMO/Gaussian, understanding the background and theory of computational chemistry would generally be beyond the scope of the inorganic course. However, I certainly want students to have some idea of what they are doing when they perform a calculation (optimization and frequency analysis of metal carbonyls, for example). I've also included here handouts I use to explain how to use W
Lanthanum gallium bismuthide
Description
This paper describes the synthesis and characterization of a new structurally interesting polybismuthide. The bonding is understood through band structure calculations and a retrotheoretical approach, analyzing the interactions of smaller substructures. Discussion is focused on the Ga-Ga bonding interactions and the weaker Ga-Bi and Bi-Bi interactions within the one-dimensional bismuth ribbons.
The Lanthanide Contraction
Description
This recent article discusses a series of isostructural complexes across the lanthanides using a multidentate ligand. In these structures, the lanthanides are all eight-coordinate, bonded to all oxygen donors. Copious structural data is presented that provides excellent experimental verification of the lanthanide contraction.
Generating LGOs (SALCs)
Description
After several days of lecturing on the topic of polyatomic molecular orbital diagrams, students break into small groups of 3-4 and form LGO’s that can be used to interact with a central atom to form a Molecular Orbital (MO) diagram. This assignment is part of a larger 4-5 week unit on MO theory.