31-P NMR spectrum of alpha-dodecatungstophosphoric acid is a combination of thirteen spectra, each spectrum representing the compound with a different number of ¹⁸³W isotopes per molecule. In order to fully interpret the spectrum one needs to apply binomial distribution to calculate the mole fractions of the molecules with various numbers of ¹⁸³W isotopes.

This LO requires an understanding of the satellites concept in NMR spectroscopy, originating from coupling with nuclei whose NMR active isotopes are not 100% abundant.

This learning objective focuses on the enzyme aconitase.  The iron-sulfur cluster is used to regulate iron in the cell and isomerize citrate for energy – two very different mechanisms.  The activity consists of an introduction to the enzyme and a student discussion on the mechanism of the isomerization of citrate to isocitrate; starting in a small group setting followed by a class debriefing.  

This is the second part of a two-day class discussion on molecular and inorganic spectroscopy. In this activity, upper level students learn about spectroscopic tecniques used in inorganic chemistry and then devise an experiment to follow the progress of a hypothetical reaction. The activity also prepares students for the inorganic laboratory "Linkage isomerism of nitrogen dioxide" in which infrared spectroscopy is used to monitor changes to the N-O vibrational stretch upon coordination to a metal.

This learning object focuses on a recent publication (Acta Crystallographia 2014, C70, 260 -266) by the Collins research group in the Department of Chemistry at The College of Wooster.  Specifically, the paper evaluates the coordination diversity of a N-donor ligand, 2-phenyl-1,10-phenanthroline(pnp) with three new pnp-metal complexes containing Au(III), Cu(II), and Pd(II) metal centers.