Intermediate Inorganic Laboratory with CURE SQ2025

Submitted by Kyle Grice / DePaul University on Wed, 04/29/2026 - 15:06
Description

In this lab we have two standard introduction labs (LUM and POR) and then a full CURE. This was the second time I ran this CURE (the first was Spring 2024).

The CURE is being published as a multi-institution ACS Symposium Series Chapter in 2026, and the materials from the CURE will be hosted in a collection on VIPEr. 

Once the chapter is published, I will add the link to it in the description. 

Synthesis of Phenyl-Substituted Poly(3-Hydroxybutyrates) with High and Tunable Glass Transition Temperatures via Sequential Catalytic Transformations (Coates)
Description

This literature discussion celebrates Dr. Geoffrey W. Coates for being the recipient of the ACS Award in Polymer Chemistry 2026 from the American Chemical Society.

Shirley Lin / United States Naval Academy Mon, 03/09/2026 - 10:27

Terminal Iron–Dinitrogen and Iron–Imide Complexes Supported by a Tris(phosphino)borane Ligand (Peters)

Submitted by Shirley Lin / United States Naval Academy on Sat, 02/28/2026 - 09:16
Description

This literature discussion LO was created for the ACS National Award Winners 2026 collection for Dr. Jonas C. Peters, the recipient of the ACS Award in Inorganic Chemistry. This LO is based on the article "Terminal Iron–Dinitrogen and Iron–Imide Complexes Supported by a Tris(phosphino)borane Ligand" published in Angewandte Chemie Int. Eng.

Symmetry of Polyhedral Dice

Submitted by Jacob Lutter / University of Southern Indiana on Tue, 02/17/2026 - 12:34
Description

This activity allows students to manipulate highly symmetric objects and find the symmetry elements that are present. 

Characterization of group VI carbonyls with bidentate phosphines

Submitted by Chip Nataro / Lafayette College on Thu, 01/15/2026 - 14:53
Description

This literature discussion comes from a paper in the Turkish Journal of Chemistry (199923, 9-14) https://journals.tubitak.gov.tr/chem/vol23/iss1/2/. In this paper, the authors report spectroscopic data for nine compounds, [M(CO)4(PP)] (M = Cr, Mo or W; PP = dppm, dppe, dppp). This is a very fundamental paper and as such, students are not expected to have had any significant coursework in inorganic chemistry.

1FLO: Addition of H2 to four-coordinate iridium

Submitted by Chip Nataro / Lafayette College on Wed, 10/22/2025 - 13:41
Description

This paper (J. Organomet. Chem. 2022, 965-966, 122317) describes the synthesis and reactivity of four-coordinate iridium compound with a tridentate ligand. This ligand is referred to in the paper as a pincer ligand which are a general class of tridentate ligands that coordinate in a mer- arrangement.

Metallocene cations and anions

Submitted by Chip Nataro / Lafayette College on Tue, 09/23/2025 - 11:39
Description

This is a really interesting paper in J. Am. Chem. Soc. (2025, 147, 34641-34646) involving a complex salt in which both the cation and anion are metallocenes. While a majority of the paper is focused on the characterization of two new compounds, it presents some excellent opportunities to practice counting electrons, one of which was a challenge to this author.

Hydrocyanation

Submitted by Chip Nataro / Lafayette College on Mon, 07/07/2025 - 07:35
Description

This literature discussion was inspired by a talk given by Dr. Nora Radu, recipient of the 2025 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry. It is a bit 'big picture' in nature in that the hydrocyanation reaction is important for the synthesis of nylon. As such, there is a significant amount of background material relating to nylon-6,6. Students will read an article from C&EN, portions of a patent, and portions of an article from J. Chem.

Determining Oxidation State: The Arrow Pushing Method

Submitted by Jared Pienkos / University of Tennessee at Chattanooga on Mon, 04/14/2025 - 10:05
Description
    1. Determining the oxidation state of atoms is foundational in chemistry. For inorganic chemistry, students must be able to accurately calculate oxidation numbers of transition metals, which can differ depending on the ligands attached.

3D Printed Crystal Structure Activity

Submitted by Chris Stromberg / Hood College on Wed, 03/19/2025 - 18:49
Description

This exercises uses beads to help show how different crystal structures are formed.  The exercise includes 3D-printed boxes with starting structures incorporated in the bottom to increase the stability of structures that students build.  The exercise also includes a number of additional 3D-printed manipulatives to help students visualize the unit cells and other properties of different crystal structures.  These include unit cells with accurate atomic and hold dimensions and several different ways to visualize the layer structures in close-packed structures.