Can donor ligands make Pd(OAc)2 a stronger oxidant? (Stahl)

Submitted by Sarah Shaner / Southeast Missouri State University on Mon, 03/20/2023 - 15:29
Description

This Literature Discussion LO was created for the 2023 ACS Inorganic Chemistry Award Winners collection. Professor Shannon Stahl was the recipient of the 2023 Organometallic Chemistry Award. This LO is based on a recent paper from the Stahl group entitled "Can Donor Ligands Make Pd(OAc)2 a Stronger Oxidant? Access to Elusive Palladium(II) Reduction Potentials and Effects of Ancillary Ligands via Palladium(II)/Hydroquinone Reox Equilibria" published in J. Am. Chem. Soc. 2020, 142, 19678-19688.

1FLO: Species distribution diagrams of iron complexes of catechols (Butler)

Submitted by Kari Stone / Lewis University on Thu, 03/09/2023 - 13:07
Description

This LO is submitted in honor of Alison Butler for her 2023 "ACS Award for Distinguished Service in Advancement of Inorganic Chemistry"

"For groundbreaking accomplishments in bioinorganic chemistry and leadership to the national and international chemistry community through the ACS Division of Inorganic Chemistry" 

National ACS Award Winners 2023 LO Collection

Submitted by Shirley Lin / United States Naval Academy on Mon, 03/06/2023 - 11:47

This collection of learning objects was created to celebrate the National ACS Award Winners 2023 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below. 

A Thousand Manipulatable Inorganic Electron-Counting Problems from Crystallography

Submitted by George Lisensky / Beloit College on Wed, 03/01/2023 - 14:40
Description

One thousand interactive organometallic and coordination complexes have been selected and prepared for practice and discovery in electron counting problems. The structures can be displayed and manipulated without requiring software installation using a web browser with JavaScript and JSmol.

Building Heteronuclear Diatomic MOs

Submitted by Andrea Van Duzor / Chicago State University on Thu, 01/26/2023 - 14:53
Description

A guided inquiry activity for students to build the MO diagram for HF based on energetic and symmetry considerations.  Students then compare their model to a standard MO diagram and examine what additional information a MO diagram conveys that the Lewis structure does not.

Phosphate Reduction by Mechanochemistry (Cummins)

Submitted by Kyle Grice / DePaul University on Fri, 01/13/2023 - 11:15
Description

This Literature Discussion LO was created for the ACS Inorganic Chemistry Award Winners. Dr. Kit Cummins was the recipient of the 2023 Frederick Hawthorne Award in Main Group Inorganic Chemistry. This LO is based on a recent paper from the group of Dr. Cummins, entitled "Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite", published in ACS Central Science20228, 332-339.

SLiThEr #42: Our Favorite Labs

Submitted by Chip Nataro / Lafayette College on Thu, 11/17/2022 - 08:29
Description

Chip Nataro (Lafayette College) hosts a live discussion covering the favorite labs that people teach. The discussion somewhat evolved into a conversation on "so, you are teaching inorganic lab for the first time...what do you do?"