Chapter 9--Stanley Organometallics

Submitted by George Stanley / Louisiana State University on Mon, 08/14/2017 - 12:23
Description

Chapter 9 from George Stanley's organometallics course, Cp

 

this chapter covers bonding and structure of metal pi-bonds, some descriptive chemistry and some historical context of sandwich compounds..

The powerpoint slides contain answers to some of the in-class exercises, so those are behind the "faculty only" wall. I share these with students after the class, but not before.

Everyone is more than welcome to edit the materials to suit their own uses, and I would appreciate being notified of any mistakes that are found.


Chapter 8--Stanley Organometallics

Submitted by George Stanley / Louisiana State University on Mon, 08/14/2017 - 12:15
Description

Chapter 8 from George Stanley's organometallics course, Arenes

 

this chapter covers bonding and structure of metal pi-bonds and some descriptive chemistry.

The powerpoint slides contain answers to some of the in-class exercises, so those are behind the "faculty only" wall. I share these with students after the class, but not before.

Everyone is more than welcome to edit the materials to suit their own uses, and I would appreciate being notified of any mistakes that are found.


Inorganic Nomenclature: Naming Coordination Compounds

Submitted by Gary Guillet / Furman University on Mon, 07/31/2017 - 15:23
Description

I do not like to take a large amount of time in class to cover nomenclature of any kind, though I want students to know the names of common ligands and the basic ideas of how coordination complexes are named.  Since it is a systematic topic I assign this guided inquiry worksheet.  I guess I think about it like learning rules for a new board game, sometimes you just have to play and learn as you go.  This assignment is meant to establish teh basica rules for naming by guiding students through what the needs are in naming, then it allows them to identify the convetions from a list of structur

Catalysis: Iron-catalyzed Arylation of Alkyl Halides

Submitted by Brad Wile / Ohio Northern University on Fri, 06/09/2017 - 15:34
Description

This LO describes a laboratory experiment in which students generate (in situ) an iron catalyst for the arylation of alkyl halides (Kumada coupling). Students pool data from the class to discern what features lead to successful catalyst systems. GC-MS or GC-FID may be used to quantify the catalytic performance of each system, and results may be expressed as % conversion, with TON/TOF values. Students gain experience proposing reasonable coordination complexes that may be formed from the catalyst precursors, and searching the literature/databases for related compounds/systems.

Investigating the toxicities of metals and identifying cadmium centers in metallothioneins

Submitted by Chantal Stieber / Cal Poly Pomona on Sat, 06/03/2017 - 14:43
Description

This activity was designed as an in-class group activity, in which students begin by using basic principles to predict relative toxicities and roles of metals in biological systems. Students then learn about the structures of metallothioneins using information from the protein data bank (PDB) and 113Cd NMR data. By the end of the activity, students will have analyzed data to identify and determine bonding models and coordination sites for multiple cadmium centers in metallothioneins. It is based on recent literature, but does not require students to have read the papers before class.

Introduction to Agostic Interactions

Submitted by Emma Downs / Fitchburg State University on Sat, 06/03/2017 - 11:59
Description

A brief introduction to agostic interactions and their importance to common organometallic mechanisms such as beta-hydride elimination. Examples of compounds containing these interactions are discussed and compared to familiar molecules such as diborane. Ways to characterize these interactions are also introduced.

Slides are based on the PNAS review Agostic Interactions in Transition Metal Compounds 

Brookheart, Green, and Parkin Proc. Natl. Acad.Sci. 2007, 104(7), 6908-6914

Literature Discussion of R3CH→ SiFR3 Agostic Interactions

Submitted by tgupta / South Dakota State University on Sat, 06/03/2017 - 11:53
Description

The set of questions in this literature discussion activity is intended to engage students in reading and interpreting scientific literature and to develop a clear and coherent understanding of agostic interactions.

Literature Discussion of "A stable compound of helium and sodium at high pressure"

Submitted by Nicole Crowder / University of Mary Washington on Sat, 06/03/2017 - 11:26
Description

This paper describes the synthesis of a stable compound of sodium and helium at very high pressures. The paper uses computational methods to predict likely compounds with helium, then describe a synthetic protocol to make the thermodynamically favored Na2He compound. The compound has a fluorite structure and is an electride with the delocalization of 2e- into the structure.

This paper would be appropriate after discussion of solid state structures and band theory.

The questions are divided into categories and have a wide range of levels.

An ion exchange method to produce metastable wurtzite metal sulfide nanocrystals

Submitted by Janet Schrenk / University of Massachusetts Lowell on Sat, 06/03/2017 - 11:25
Description

In this literature discussion, students use a paper from the literature to explore the synthesis, structure, characterization (powder XRD, EDS and TEM) and energetics associated with the production of a metastable wurtzite CoS phase. Students also are asked define key terms and acronyms used in the paper; identify the goal of the experiments and determine if the authors met their goal. They examine the fundamental concepts around the key crystal structures available.  

 

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