In this experiment, students will synthesize and characterize one of three Ag(I) cyanoximate complexes as potential antimicrobial agents for use in dental implants. This experiment combines simple ligand synthesis, metalation and characterization, and a biomedical application. The complexes are both air and light stable.
Upper division literature discussion of a JACS paper on electrocatalysis. This activity serves as an introductory look at the paper as a homework assignment to prepare the student for a more in depth class discussion.
This is the procedure for a Fe(III) catalyzed synthesis of aspirin, an alternative to the traditionally sulfuric acid catalyzed synthesis of aspirin. The prep compares and contrasts the Bronsted acid catalyzed esterification reaction with a Lewis acid iron (III) catalyzed pathway. This can be used in different courses at different levels, but is it written for a general/intro level chemistry course.
Examples taken from the literature for the six palladium-catalyzed coupling reactions used in organic chemistry.
The Materials Project is part of the Materials Genome Initiative that uses high-througput computing to uncover the properties of inorganic materials.
It's possible to search for materials and their properties
It employs high-throughput computation approaches and IT to create a system that can be used to predict properties and construct phase diagrams andPourbaix diagrams.
This is just a cool little website I just happened to stumble upon today while looking for something else at the RSC site. It comes from China, and it is pretty!
Collection of Safety LOs from VIPEr
The resources on this website will help students learn concepts in materials chemistry, solid state chemistry, and nanoscience. The website provides links to
The slides provide review questions for a senior-level treatment of the spectroscopy and reactivity of metal carbonyl complexes. These are intended to be dispersed through one to three class periods.
The first slide is a review of electron counting and the 18-electron rule.
The second slide quizzes the students on the relationship between the electron-density of the metal center and the strength of the C-O bonds in the carbonyl ligands. It is intended to be given after a discussion of how IR can be used to assess the strength of M-C and C-O bonds in the compounds.