National ACS Award Winners 2022 LO Collection
This collection of learning objects was created to celebrate the National ACS Award Winners 2022 who are members of the Division of Inorganic Chemistry. The list of award winners is shown below.
SLiThErs - Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable
Chip Nataro / Lafayette College
Thu, 12/17/2020 - 14:18
A collection of all of the IONiC VIPEr SLiThErs (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable). These events are short presentations on a topic followed by a period of discussion between the presenter and live participants. Each of these events is recorded and posted to the IONiC VIPEr YouTube Channel.
Coordination Bonding with Main Group Metals(?)
Description
This Literature Discussion considers the synthesis of the first carbene-bismuthinidene complex by Gilliard and coworkers in 2019. This molecule serves as an illustration of different bonding models, as it can be described by multiple resonance structures invoking fully covalent, zwitterionic, and coordinate/dative bonding forms. Students analyze these resonance structures and their geometrical implications, then compare to the experimental structural evidence to come to a conclusion about which bonding model(s) best describe this molecule!
Literature Discussion Group Project
Wes Farrell / United States Naval Academy
Mon, 08/05/2024 - 14:23
Description
This is a literature-based end of semester project. After a semester of introducing literature in the form of typical literature discussions, this assignment is given to small groups. It may be easily amended or added to. Each group is provided with a paper and accompanying questions that are similar to the literature discussions they have done over the semester. They then must use these guiding questions to assemble a presentation to the class. The topics chosen and the guiding questions are designed to provide students with a taste of the many areas of inorganic chemistry that are no
Literature discussion for “Synthesis and characterization of a formal 21-electron cobaltocene derivative.”
Description
This is a literature discussion regarding electron counting. It involves several opportunities for students to use CBC to determine electron counts themselves. Then, it demonstrates the first case of a 21-electron complex, which leads to great discussion regarding the 18-electron rule. Throughout the discussion, students are introduced to many structural and spectrochemical analyses, some of which may be new to them.
Incorporating hard-soft acid-base theory to create transition-metal and oxidation-state specific biological probes (Chang)
Description
This literature discussion was created on invitation as part of a broad collection of learning objects celebrating Spring 2024 ACS award winners conducting research in Inorganic Chemistry. This learning object is in celebration of Prof. Christopher J.
Visible Light-Absorbing Ruthenium Complexes: Choosing a Final Project in Inorganic Chemistry Laboratory from Two Real-World Applications
Description
Laboratory Project Summary:
Students in an upper level Inorganic Chemistry lab course are given a choice between two final lab projects. Both projects involve the synthesis of visible light-absorbing ruthenium complexes, however the subsequent application of these complexes correspond to different subfields within inorganic chemistry. This feature allows them to pursue a project that continues to develop their synthetic, data-analysis, and writing skills while pursuing one that most closely aligns with their interests.
Lewis Base Stabilized Dichlorosilylene (Roesky)
Description
This literature discussion LO was created for the ACS National Award Winners 2024 collection. Dr. Herbert Roesky was the recipient of the 2024 Frederic Stanley Kipping Award in Silicon Chemistry. This LO is based on the article "Lewis Base Stabilized Dichlorosilylene" published in Angewandte Chemie 2009, 121, 5793-5796.
Guided Literature Reading and Discussion: Synthesis & Characterization of Reduced Borafluorene Monoanions
Description
Guided literature reading of Angew. Chem. Int. Ed. 2021, 60, 13065-13072: Stabilization of the Elusive 9-Carbene-9-Borafluorene Monoanion.
There are three components of the assignment:
Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions by Robert J. Gilliard Jr.
Niharika K Botcha / Carnegie Mellon University
Fri, 06/30/2023 - 10:27
Description
This literature discussion on the Hot Paper communication in Chemistry, A European Journal; highlights the first examples of borepinium and borfluorenium cations whose optical properties can be tuned and also the very first reported example of thermochromism in these cationic species. R. J. Gilliard, Chem. Eur. J. 2019, 25, 12512. https://doi.org/10.1002/chem.201903348