Chapter 15--Stanley Organometallics

Submitted by George Stanley / Louisiana State University on Mon, 08/14/2017 - 14:02
Description

Chapter 15 from George Stanley's organometallics course, Hydrogenation

this chapter covers hydrogenation catalysis and has many literature examples.

The powerpoint slides contain answers to some of the in-class exercises, so those are behind the "faculty only" wall. I share these with students after the class, but not before.

Everyone is more than welcome to edit the materials to suit their own uses, and I would appreciate being notified of any mistakes that are found.


Chapter 14--Stanley Organometallics

Submitted by George Stanley / Louisiana State University on Mon, 08/14/2017 - 13:57
Description

Chapter 14 from George Stanley's organometallics course, Catalysis Introduction

 

this chapter covers an introduction to catalysis and includes many questions directly from the literature.

The powerpoint slides contain answers to some of the in-class exercises, so those are behind the "faculty only" wall. I share these with students after the class, but not before.

Everyone is more than welcome to edit the materials to suit their own uses, and I would appreciate being notified of any mistakes that are found.


Chapter 13--Stanley Organometallics

Submitted by George Stanley / Louisiana State University on Mon, 08/14/2017 - 12:51
Description

Chapter 13 from George Stanley's organometallics course, Migratory Insertion and Elimination

 

this chapter covers migratory insertion and elimination reactions.

The powerpoint slides contain answers to some of the in-class exercises, so those are behind the "faculty only" wall. I share these with students after the class, but not before.

Everyone is more than welcome to edit the materials to suit their own uses, and I would appreciate being notified of any mistakes that are found.


Chapter 12--Stanley Organometallics

Submitted by George Stanley / Louisiana State University on Mon, 08/14/2017 - 12:45
Description

Chapter 12 from George Stanley's organometallics course, Oxidative Addition and Reductive Elimination

 

this chapter covers oxidative addition and reductive elimination reactions.

The powerpoint slides contain answers to some of the in-class exercises, so those are behind the "faculty only" wall. I share these with students after the class, but not before.

Everyone is more than welcome to edit the materials to suit their own uses, and I would appreciate being notified of any mistakes that are found.


Chapter 11--Stanley Organometallics

Submitted by George Stanley / Louisiana State University on Mon, 08/14/2017 - 12:40
Description

Chapter 11 from George Stanley's organometallics course, Ligand Substitution

 

this chapter covers ligand substitution reactions.

The powerpoint slides contain answers to some of the in-class exercises, so those are behind the "faculty only" wall. I share these with students after the class, but not before.

Everyone is more than welcome to edit the materials to suit their own uses, and I would appreciate being notified of any mistakes that are found.


Introduction to Agostic Interactions

Submitted by Emma Downs / Fitchburg State University on Sat, 06/03/2017 - 11:59
Description

A brief introduction to agostic interactions and their importance to common organometallic mechanisms such as beta-hydride elimination. Examples of compounds containing these interactions are discussed and compared to familiar molecules such as diborane. Ways to characterize these interactions are also introduced.

Slides are based on the PNAS review Agostic Interactions in Transition Metal Compounds 

Brookheart, Green, and Parkin Proc. Natl. Acad.Sci. 2007104(7), 6908-6914

An ion exchange method to produce metastable wurtzite metal sulfide nanocrystals

Submitted by Janet Schrenk / University of Massachusetts Lowell on Sat, 06/03/2017 - 11:25
Description

In this literature discussion, students use a paper from the literature to explore the synthesis, structure, characterization (powder XRD, EDS and TEM) and energetics associated with the production of a metastable wurtzite CoS phase. Students also are asked define key terms and acronyms used in the paper; identify the goal of the experiments and determine if the authors met their goal. They examine the fundamental concepts around the key crystal structures available.  

 

Quantum Dot Growth Mechanisms

Submitted by Chi / United States Military Academy on Sat, 06/03/2017 - 11:01
Description

This literature article covers a range of topics introduced in a sophomore level course (confinement/particle-in-a-box, spectroscopy, kinetics, mechanism) and would serve as a an end-of-course integrated activity, or as a review activity in an upper level course.

Ligand based reductive elimination from a thorium compound

Submitted by Chip Nataro / Lafayette College on Tue, 05/23/2017 - 16:52
Description

This literature discussion is based on a paper describing the ligand-based reductive elimination of a diphosphine from a thorium compound (Organometallics2017, ASAP). The thorium compound contains two bidentate NHC ligands providing an opportunity to discuss the coordination of these ligands. The ligand-based reduction is very subtle and would be challenging for students to pick up without some guidance. The compound undergoing reductive elimination also presents an excellent introduction into magnetic nonequivalence and virtual coupling.

Johnson Matthey Catalytic Reaction Guide

Submitted by Sheila Smith / University of Michigan- Dearborn on Tue, 04/11/2017 - 12:11
Description

This guide, available in print, online and in an app, allows users to look up appropriate catalysts and conditions to accomplish a wide variety of reactions.