Stoichiometry Roadmap
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Backdonation Board Pins
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Soluble Methane Monooxgenase Spectroscopy
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Determining the reactive intermediates in metalloenzymes is a very involved task, and requires drawing from many different spectroscopies and physical methods. The facile activation and oxidation of methane to produce methanol is one of the "holy grails" of inorganic chemistry. Strategies exist within materials science and organometallic chemistry to activate methane, but using the enzyme methane monooxygenase, nature is able to carry out this difficult reaction at ambient temperatures and pressures (and in water, too!).
Dioxygen Activation in Non-heme Iron Enzymes
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This lecture provides a short introduction to the other half of biological iron chemistry: enzymes that do not contain a porphyrin group that ligates the iron atom. There are several important applications for non-heme iron in cells, both mammalian and bacterial. Oxygen activating non-heme iron enzymes fall into a few basic categories and includes mononuclear iron monooxygenases and dioxygenases, and binuclear iron monooxygenases. The requirements to activate and utilize dioxygen will be given.
Electrocatalysis and Proton Reduction
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These slides provide a brief introduction to the concept of electrocatalysis using the glyoximato cobalt catalysts for hydrogen production recently examined by Peters, Gray, and others. They provide a suitable introduction to the topic for students interested in reading the primary literature on these topics.
Exploring the Nanoworld Innovating through Materials from the University of Wisconsin Madison
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This is a great web resource for all types of nano materials. There are lesson plans, demos, activites, labs and lots of background information. It is very easy to navigate and there are videos of the labs so you can see each step - very useful when doing a type of synthesis or technique new to you.
An Introduction to Electrocatalysis: Hydrogen Evolution from Mono and Binuclear Cobalt Complexes
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This learning object was developed at the 2012 NSF sponsored cCWCS VIPEr workshop at UNC-CH where we were fortunate to hear Jillian Dempsey present this research that has appeal to students. This work focuses on an exciting and promising strategy to develop new technology to support a solar energy economy. This literature discussion leads students through a current application in the field of electrocatalysis.
Literature Discussion on “Mechanisms for the Activation of Carbon Monoxide via Oxorhenium Complexes.”
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This is intended as a guided reading assignment for the JACS Communication, “Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes” by Smeltz, Boyle, and Ison; J. Am. Chem. Soc. 2011, 133, 13288-13291. This article will expose students to newly published research and novel reaction mechanisms. It will require students to apply their knowledge of electron counting and organometallic mechanisms.
C(sp3)-F Activation through an Initial C(sp3)-H Activation Mechanism
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This paper is from a Science article from Alan Goldman’s group at Rutgers University. It was one of the literature articles that was assigned during the IONiC VIPEr Workshop in July 2012. In conjunction with reading the article, workshop participants attended a seminar presented by Alan Goldman on this work.
Colored Note Cards as a Quick and Cheap Substitute for Clickers
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For many years I have resisted using clickers, mainly because at our university there is no standard universal clicker. I wanted to keep student costs as low as possible but also desired the type of live feedback during a lecture that clicker questions can provide. In both my general chem. (200-300 students) and upper division courses (50-75 students), I now pass out 4 or 5 colored notecards on the first day of class and make sure everyone has one of each color.