Inorganic Chemistry

Submitted by Martin McPhail / University of West Georgia on Thu, 05/19/2022 - 15:19
Description

The wave nature of electrons is applied to atomic structure and periodic trends. Inter and intramolecular bonding models are used to interpret the chemical and physical properties of various materials, from simplistic diatomic molecules to structurally complex molecular and ionic systems.

Guess What: An Inorganic Chemistry Board Game

Submitted by Brad Wile / Ohio Northern University on Mon, 04/25/2022 - 17:46
Description

"Guess Who?" is a two player board game in which the object is to guess the identity of a character by asking questions about their appearance or features. This activity uses a similar game mechanic to identify concepts, models, and historical figures from inorganic chemistry. 

The ditungsten tetracarboxylate story (Sattelberger)

Submitted by Joanne Stewart / Hope College on Tue, 03/15/2022 - 09:37
Description

This literature discussion learning object examines the first reported synthesis in 1983 of the long anticipated quadruply bonded ditungsten tetracarboxylate dimers by Dr. Al Sattelberger and co-workers. This LO is part of a special VIPEr collection honoring the 2022 ACS National Award recipients in the field of inorganic chemistry. Alfred P. Sattelberger was the recipient of the 2022 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry.

Spectroscopic, Structural, and Computational Analysis of [Re(CO)3(dippM)Br]n+ (Nataro)

Submitted by Shirley Lin / United States Naval Academy on Sat, 03/12/2022 - 06:17
Description

This literature discussion will guide students through an article that applies spectroscopic, structural, and computational analyses to a family of compounds of the type [Re(CO)3(dippM)Br]n+  (dippM = 1,1’-bis(diisopropyl)phosphino metallocene, M = Fe, n= 0 or 1; M = Co, n = 1).

Toward the Design of Phosphorescent Emitters of Cyclometalated Earth-Abundant Nickel(II) and Their Supramolecular Study (Yam)

Submitted by Kyle Grice / DePaul University on Tue, 03/08/2022 - 15:15
Description

This LO was created to celebrate Dr. Vivian W.-W. Yam's 2022 ACS Award, the Josef Michl Award in Photochemistry. These questions are written to help guide class discussion about this paper and the complexes in it. This LO would be good for an organometallics class or similar upper-division inorganic chemistry class. 

Evidence of a homogeneous trinuclear Rh(I)-Cu(II)-Rh(I) catalyst for benzene C-H oxidative addition and styrene production (Gunnoe)

Submitted by John Lee / University of Tennessee Chattanooga on Wed, 03/02/2022 - 10:26
Description

The literature discussion is based on a manuscript by Gunnoe and coworkers (ACS Catal. 2021, 11, 5688-5702. DOI: 10.1021/acscatal.1c01203). The paper presents mechanistic studies of catalytic oxidative conversion of arenes and olefins to alkenyl arenes with a focus on styrene production.

VIPEr nanoCHAt : NeWBiEs Spring 2022 Learning Objects

Submitted by Shirley Lin / United States Naval Academy on Wed, 02/02/2022 - 18:07

This collection accompanies the IONiC VIPEr nanoCHAt video series NeWBiEs, recorded in Spring 2022. This series is comprised of weekly conversations with two IONiC members, Wes Farrell and Shirley Lin from the US Naval Academy, as they taught a foundation-level inorganic chemistry course for the first time. The LOs discussed in the videos are included in this collection.