Pre-Equilibria Reaction Mechanism as a Strategy to Enhance Rate and Lower Overpotential in Electrocatalysis (Berben)
This literature Discussion LO was created for the 2024 ACS Inorganic Chemistry Award Winners Collection. Professor Louise A.
A collection of all of the IONiC VIPEr SLiThErs (Supporting Learning with Interactive Teaching: a Hosted, Engaging Roundtable). These events are short presentations on a topic followed by a period of discussion between the presenter and live participants. Each of these events is recorded and posted to the IONiC VIPEr YouTube Channel.
This literature Discussion LO was created for the 2024 ACS Inorganic Chemistry Award Winners Collection. Professor Louise A.
This was the 57th SLiThEr, presented by Dr. George Stanley, retired professor from LSU. It was a very interesting story and would be a valuable lesson to students about proper characterization and working with challenging and paramagnetic systems.
I regularly give an oral exam instead of a written exam in my junior and senior level organometallics seminar course. The course focuses on the primary literature, discussion of advanced topics, and asking questions. A written exam would not evaluate the students' abilities on the important skill development they learned in the class. Besides, I am better able to gauge when a student has no idea about a certain topic, or just needs a little nudge in order for them to demonstrate that they actually understand 95% of it.
I saw Amanda Cook present this work (and another paper, Organometallics, 2022, 41, 997) at the Organometallics Gordon Conference in summer 2023 and while I was furiously taking notes, I knew that I wanted to teach this paper. The paper elucidates the mechanism of oxidative addition of tertiary silanes to palladium zero phosphine complexes.
I am moving away from teaching the Goldberg paper (still one of my favorites) and instead wanted to teach just the highlights as part of my seminar class in organometallic chemistry this fall. I created this shorter version of the activity to use in class. I did NOT have them read the paper in advance, hence the summaries in the LO itself.
Students perform weekly laboratory experiments to explore and apply concepts covered in the lecture
component of the course.
CHEM 4310 is an in-depth review of modern inorganic chemistry. Topics will include symmetry, acids and bases, reduction-oxidation reactions, periodic trends, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and material chemistry. The course will meet for three hours of lecture and three hours of laboratory per week.
From the course catalog: The chemistry of the Main Group elements and the transition metals are studied with emphasis on the properties, structures, and reactivities of these elements and their compounds.