This is a basic introduction to Enemark-Feltham that can be used in conjunction with any literature that has Iron nitrosyls in it. I made this as a follow up to the work that came ouf of the 2018 VIPEr workshop in UM-Dearborn.
The application of physio-chemical principles to understanding structure and reactivity in main group and transition elements. Valence Bond, Crystal Field, VSEPR, and LCAO-MO will be applied to describe the bonding in coordination compounds. Organometallic and bio-inorganic chemistry will be treated, as will boranes, cluster and ring systems, and inorganic polymers. The laboratory will involve both synthetic and analytic techniques and interpretation of results.
Rules for quantum numbers are confusing but not arbitrary. They are based on wave mathmatics, and once laid out properly are symmetric and beautiful. Within four animation-clicks of the first slide of this PowerPoint Presentation, this beauty will unfold. I do not exaggerate to say, faculty members will be agape and students will say, "Why didn't you show us this before." No other presentation shows in as elegant a way the relationship between 1) n, l and ml, 2) the ordering of orbitals in hydrogen-like atoms, and 3) the ordering of orbitals in the periodic table (along with
The activity is designed to be a literature discussion based on Nicolai Lehnert's Inorganic Chemistry paper, Mechanism of N-N Bond Formation by Transition Metal-Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases. The discussion questions are designed for an advanced level inorganic course.
Inorganic chemists often use IR spectroscopy to evaluate bond order of ligands, and as a means of determining the electronic properties of metal fragments.
In honor of Professor Richard Andersen’s 75th birthday, a small group of IONiC leaders submitted a paper to a special issue of
Fundamental principles of inorganic chemistry, including: states of matter; modern atomic and bonding theory; mass and energy relationships in chemical reactions; equilibria; acids and bases; descriptive inorganic chemistry; solid state structure; and electrochemistry. Periodic properties of the elements and their compounds are discussed (3 hours lecture, 1 hour recitation).
Modern theories of atomic structure and chemical bonding and their applocations to molecular and metallic structures and coordination chemistry.
Introduction to classical and modern techniques for
synthesizing inorganic compounds of representative and transition
metal elements and the extensive use of IR, NMR, mass, and UV-visible
spectroscopies and other physical measurements to characterize
products. Syntheses and characterization of inorganic and organic
materials/polymers are included. Attendance at departmental seminars
required. Lecture, laboratory, oral presentations.