This 5 slides about will introduce students to the concept of photoinduced electron transfer. These slides go over the energics of photoinduced electron transfer, which implements basic concepts of photochemistry and electrochemistry. The photoinduced electron transer properties of ris-(2,2'-bipyridine)-ruthenium(II) is used as an example.
This five slides about chemical exchange transfer (CEST) discusses the magnetic properties of paramagnetic metal ions and their use as MR imaging agents. This includes tranditional contrast agents that affect the relaxation rate of nearby water protons and paramagnetic shift reagents suitable for CEST imaging applications. A recent redox-active cobalt complex is presented as an innovative agent for mapping redox imbalances in vivo.
Anne asked the students in her junior/senior inorganic course to develop their own literature discussion learning objects and lead the rest of the class in a discussion of their article. Each student chose one article from a list of suggestions provided. Student Hayley Johnston chose this article describing a Mn-containing catalyst for carbon dioxide reduction (Jonathan M. Smieja, Matthew D. Sampson, Kyle A. Grice, Eric E. Benson, Jesse D. Froehlich, and Clifford P.
This is a 90 minute talk by Fraser Armstrong of Oxford University (http://armstrong.chem.ox.ac.uk) explaining the electrochemistry of proteins immobilized on surfaces. The talk was presented at the 3rd Bioinorganic Workshop in 2014 at Pennsylvania State University. The talk contains an excellent basic tutorial on simple electron transfer on immobilized substrates using simple iron sulfur proteins as the primary example.
During my junior/senior level inorganic course, we did several guided literature discussions over the course of the semester where the students read papers and answered a series of questions based on them (some from this site!). As part of my take home final exam, I gave the students an open choice literature analysis question where they had the chance to integrate topics from the semester into their interpretation of a recent paper of their own choice from Inorganic Chemistry, this time with limited guidance.
(1) Student choses and reads a journal article of his/her choice that is related to a topic we have discussed during the semester. (i.e. atomic structure, MO theory, group theory, solid state structure, band theory, coordination chemistry, organometallics, catalysis). Suggested journals include, but are not limited to JACS, Inorg. Chem., Organometallics, Angew. Chem., JOMC, Chem. Comm.)
(2) Student answers the following questions regarding their chosen article:
(a) Describe, in 1 or 2 sentences the goal of this work.
Synthesis of ammonium decavanadate, and analysis via IR, UV-Vis and quantitative titration. Time: 1.5 lab periods
Purpose
The purpose of this lab experiment is to expose students to the synthesis of a colored POM, and to connect the use of standard analytical techniques to this new type of compound. It introduces the use of IR spectroscopy of inorganic materials.
Introduction
This website is a free and comprehensive resource that is a collection of open college courses that spans videos, audio lectures, and notes given by professors at a variety of universities. The website is designed to be friendly and designed to be easily accessed on any mobile device.
Determining the reactive intermediates in metalloenzymes is a very involved task, and requires drawing from many different spectroscopies and physical methods. The facile activation and oxidation of methane to produce methanol is one of the "holy grails" of inorganic chemistry. Strategies exist within materials science and organometallic chemistry to activate methane, but using the enzyme methane monooxygenase, nature is able to carry out this difficult reaction at ambient temperatures and pressures (and in water, too!).
These slides provide a brief introduction to the concept of electrocatalysis using the glyoximato cobalt catalysts for hydrogen production recently examined by Peters, Gray, and others. They provide a suitable introduction to the topic for students interested in reading the primary literature on these topics.