Literature Discussion of "A stable compound of helium and sodium at high pressure"

Submitted by Nicole Crowder / University of Mary Washington on Sat, 06/03/2017 - 11:26
Description

This paper describes the synthesis of a stable compound of sodium and helium at very high pressures. The paper uses computational methods to predict likely compounds with helium, then describe a synthetic protocol to make the thermodynamically favored Na2He compound. The compound has a fluorite structure and is an electride with the delocalization of 2e- into the structure.

This paper would be appropriate after discussion of solid state structures and band theory.

The questions are divided into categories and have a wide range of levels.

Redox Chemistry and Modern Battery Technology

Submitted by Zachary Tonzetich / University of Texas at San Antonio on Mon, 04/10/2017 - 11:33
Description

This In-Class Activity is a series of instructor-guided discussion questions that explore lithium-ion batteries through the lens of simple redox chemistry. I use this exercise as a review activity in my Descriptive Inorganic Chemistry course to help prepare for examinations. However, my primary purpose with this exercise is to impress upon students how basic concepts in redox chemistry and solid-state structure are directly relevant to technologies they use everyday.

Close Packing Activity

Submitted by George Lisensky / Beloit College on Tue, 06/28/2016 - 11:47
Description

Many extended structures can be viewed as close-packed layers of large anions, with the smaller cations fitting in between the anions. Larger holes between close-packed anions can hold cations with octahedral coordination. Smaller holes between close-packed anions can hold cations with tetrahedral coordination. The online jsmol resources show these layers and their holes.

Online Homework for a Foundations of Inorganic Chemistry Course

Submitted by Sabrina Sobel / Hofstra University on Mon, 06/27/2016 - 18:08
Description

The Committee on Professional Training (CPT) has restructured accreditation of Chemistry-related degrees, removing the old model of one year each of General, Analytical, Organic, and Physical Chemistry plus other relevant advanced classes as designed by the individual department. The new model (2008) requires one semester each in the five Foundation areas: Analytical, Inorganic, Organic, Biochemistry and Physical Chemistry, leaving General Chemistry as an option, with the development of advanced classes up to the individual departments.

Solid State Stoichiometry Activity

Submitted by George Lisensky / Beloit College on Mon, 06/27/2016 - 17:11
Description

The goal of this activity is to have students calculate the empirical formula of a compound given the contents of a unit cell. 

A repeating building block, or unit cell, is used to represent extended structures since shifting a unit cell along its edges by the length of the edge will exactly replicate the extended structure.

Solid State Stoichiometry Online

Submitted by George Lisensky / Beloit College on Mon, 06/27/2016 - 15:10
Description

The page has JSmol structures for unic cells including cubic, body centered cubic, and face centered cubic unit cells as well as for CsCl, Ni3Al, Cu2O, NaCl, CaF2, ZnS, diamond, Li3Bi, NaTl, NiAl and ReO3The advanced page also has triclinic, monoclinic, hexagonal, orthorhombic, and tetragonal cells with all possible centering.

Metal and Ionic Lattices Guided Inquiry Worksheet

Submitted by Adam Johnson / Harvey Mudd College on Mon, 05/16/2016 - 14:00
Description

This is a short worksheet that guides students through simple metal lattices (SCP, CCP, HCP) and how filling holes in these lattices results in ionic lattices (NaCl, CsCl, fluorite, etc.).

The worksheet was used as an in-class activity after students had read about the material in the text. This activity is probably suitable for first-year students, though I used it with juniors/seniors.

Crystal Field Theory and Gems--Guided Inquiry

Submitted by Adam Johnson / Harvey Mudd College on Sat, 05/14/2016 - 21:42
Description

The colors of transition metal compounds are highly variable. Aqueous solutions of nickel are green, of copper are blue, and of vanadium can range from yellow to blue to green to violet. What is the origin of these colors? A simple geometrical model known as crystal field theory can be used to differentiate the 5 d orbitals in energy. When an electron in a low-lying orbital interacts with visible light, the electron can be promoted to a higher-lying orbital with the absorption of a photon. Our brains perceive this as color.

Nanomaterials Chemistry

Submitted by Anne Bentley / Lewis & Clark College on Wed, 03/23/2016 - 15:49

This list includes a number of LOs to help in teaching nanomaterials subjects; however, it is not exhaustive.

Updated June 2018.

PVEducation.org: A resource for teaching solid-state chemistry and photovoltaics

Submitted by Kate Plass / Franklin & Marshall College on Tue, 06/30/2015 - 13:49
Description

This is a website that teaches students about various aspects of pn-junction photovoltaics, from basics about solar illumination, to solid state chemistry, to PV module design. There are numerous animations demonstrating facets of solid-state chemistry and light absorption. Here I will describe how I have used sections 3.1 Basics and 3.2 Generation in Inorganic Chemistry in the context of a specific laboratory application, but the site could have many more uses.