The Synthesis and Electronic Structure of [NiX4]2- Complexes and the Role of Crown Ethers in Inorganic Synthesis

Submitted by Wes Farrell / United States Naval Academy on Thu, 06/06/2019 - 15:05
Description

This literature discussion aims to have students in an advanced inorganic chemistry course interpret reaction schemes and electronic spectra, relate chemical formulae to molecular structure, and gain an understanding of how inorganic synthesis is planned and executed.  Students should gain an understanding of how counterions and crown ethers affect structure. Question 7 may be expanded to ask students to why pi-donor ability affects ligand field splitting, or as an introfuction to this topic.

An associated 1FLO based on this paper is linked in the related content.

 

Inorganic Chemistry

Submitted by Joanne Smieja / Gonzaga University on Wed, 06/05/2019 - 11:46
Description

Introduction to foundational concepts in inorganic chemistry with emphasis on atomic structure, bonding, and reactivity. Topics will include nuclear chemistry, quantum mechanics, periodic trends, covalent bonding, ionic bonding, metallic bonding, coordinate covalent bonding, acid-base chemistry, electrochemistry, and thermodynamics.

Zinc-Zinc Bonds (Expanded and Updated)

Submitted by Wes Farrell / United States Naval Academy on Wed, 06/05/2019 - 11:42
Description

This paper in Science reports the synthesis of decamethyldizincocene, a stable compound of Zn(I) with a zinc-zinc bond. In the original LO, the title compound and the starting material, bis(pentamethylcyclopentadienyl)zinc, offer a nice link to metallocene chemistry, electron counting, and different modes of binding of cyclopentadienyl rings as well as more advanced discussions of MO diagrams.

Advanced Inorganic Chemistry

Submitted by Jeremy R. Andreatta / Worcester State University on Tue, 06/04/2019 - 23:07
Description

This course is a survey of the chemistry of the inorganic elements focusing on the relationship between electronic structure, physical properties, and reactivity across the periodic table. Topics to be covered include: atomic structure, chemical bonding, group theory, spectroscopy, crystal field theory, coordination chemistry, organometallic chemistry and catalysis, and bioinorganic chemistry.  Prerequisites: Successful completion of CH120, CH121, (with a C- or better) and CH 301 (suggested)

Inorganic Chemistry

Submitted by Colleen Partigianoni / Ferris State University on Tue, 06/04/2019 - 22:54
Description

Course Description: An overview course covering the fundamental principles and theories of inorganic chemistry, with emphasis on the chemistry of d-block elements. Included topics are molecular structure, electronic structure and spectra, bonding descriptions and reaction mechanisms of coordination complexes along with an introduction to organometallic compounds of d-block elements and an introduction to molecular symmetry and point groups.

Inorganic Chemistry

Submitted by Maria Carroll / Providence College on Tue, 06/04/2019 - 22:53
Description

Structure and bonding in inorganic systems are the general subjects of this course. Both main group and transition metal chemistry are discussed.

Inorganic Chemistry

Submitted by Leon / Stonehill College on Mon, 06/03/2019 - 11:32
Description

This course covers fundamentals of central topics in inorganic chemistry from historical to modern-day perspectives.  Topics include: coordination compounds (history, structure, bonding theories, reactivity, applications); solid state chemistry (crystals, lattices, radius ratio rule, defect structures, silicates & other minerals); and descriptive chemistry of the elements.