Fivefold Bonding in Cr(I) Dimer
This paper describes the synthesis and characterization of a Cr(I) dimer with a very short Cr-Cr distance. Computational studies support fivefold bonding between the chromium atoms. I have used this paper to introduce metal-metal multiple bonds and discuss the molecular orbital interactions of homonuclear diatomics including d-orbitals. More generally, it is a nice example to stimulate the discussion of what constitutes a bond and the various interpretations of bond order.
Nitrogenase primary literature
Lanthanum gallium bismuthide
Fluoro Analogue of Wilkinson's Catalyst
Miessler and Tarr: Inorganic Chemistry, 3rd. Ed
Miessler and Tarr is an inorganic textbook which is is best suited to an upper-division one-semester inorganic course, though there is more material than can be covered in a single semester, so some choice of topics is necessary. It is very well suited for a course oriented around structure, bonding, and reaction chemistry of transition metal compounds, but is very limited in its treatment of solids, main-group, descriptive chemistry, and bioinorganic. Pchem would be helpful but is not necessary. In particular, the treatment of MO theory is very in-depth. The quality of end-of chapter p
Zinc-Zinc Bonds
Housecroft and Sharpe: Inorganic Chemistry, 3ed
Housecroft and Sharpe (Inorganic Chemistry, 3ed): This is a comprehensive inorganic textbook designed primarily for students at the Junior/Senior level. P-Chem would not be needed as a prerequisite for this text, but would be helpful. It includes both theoretical and descriptive material along with special topics, enough for a two semester course though it is easily adaptable to a one-semester "advanced inorganic" course by choosing only some topics. It is written in a clear and generally readable style and the full-color graphic contribute to student understanding.
Literature Discussion: Synthesis, Structure, and Reactivity of a Stabilized Calcium Carbene: R2CCa
Literature Discussion: "Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds"
This is a literature discussion assignment in which students read a paper, come up with their own answers to the provided questions (and submit them). This is followed by a general in-class discussion on the paper. This particular article deals with hydrosilyation of carbonyl compounds by a Re catalyst and describes the mechanism and kinetics in detail. I found it a good paper to help students connect their P-chem (and inorganic) kinetics with a "real" system. As part of the literature assignment, I also ask students to draw an MO diagram of a simple substrate (for review).
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