Bonding and Electronic Structure of a 14-electron W(II) bound to 4-electron pi-donors
This paper is a meaty communication that covers novel bonding of 4 e- π-donors to a 14-electron species. Requires students to apply their knowledge of electron counting and organometallic bonding to ligands that are acting in novel ways. This also includes exercises dealing with chemical information and general questions that require students to put the science in context.
The 18 Electron Guideline: A Primer
This consists of two parts (and a solution, which is linked below under "Related Resources", but for which you will need a faculty privileges): a primer for students (best if handed out prior to class so that students can read it beforehand, or delivered in pre-lecture format) and a worksheet. The worksheet is designed to be done in small groups with assistance from an instructor. In very large classes, in which the instructor cannot circle amongst the groups, the instructor can work through each example after the groups have a few minutes to work the problem on their own.
Inorganic Chemistry Just Makes You Want to Sing!
Here is a fun way to learn about inorganic chemistry! These songs were composed and passed along to me by Tom Mallouk at Penn State with his permission to post here on VIPEr. I Can't Get No Bragg Diffraction was a joint effort put together one year at a Gordon Research Conference on Solid State Chemistry. Sorry, no recording! The tune n-doped, recorded by the Band Edges, covers the electronic structure behind semiconductor devices. Download the lyrics for both and the mp3 file for n-doped! There is a
Putting electrochemistry to use: Design of new lithium-ion battery anodes
Assessing Chemical Hazards
This is a short activity I developed to help my students interpret Material Safety Data Sheets (MSDS). Students rank unknown compounds from least safe to most safe, and the compounds' identities are revealed. The class discusses other factors to consider in evaluating the safety of an experiment. The "MSDS activity" word document contains a more full description.
F-elements Lecture Material
Sherlock Holmes in Transition-Metal Chemistry
Electron Counting and a Catalytic Reaction
Speed-Dating, Chemistry Style: HSAB Theory
This is an interactive Challenge in which students have to find others in the room with whom they "match" as a hard or soft acid or base. It brings to life the way inorganic chemists think about HSAB. Inorganic Challenges are exercises designed to be solved by a small group of students. Some Challenges practice a problem-solving algorithm, some reinforce important concepts, and some involve creativity or games.
Pagination
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