Inorganic Chemistry

Submitted by Gary Guillet / Furman University on Thu, 04/25/2019 - 16:02
Description

Introduces students to a broad overview of modern inorganic chemistry. Included are considerations of molecular symmetry and group theory, bonding and molecular orbital theory, structures and reactivities of coordination compounds, organometallic chemistry, catalysis and transition metal clusters. Laboratory experiences will include the measurement of several important features of coordination compounds, such as their electronic spectra and paramagnetism, as well as the synthesis and characterization of organometallic compounds.

Redox-switch polymerization catalysis

Submitted by Chip Nataro / Lafayette College on Tue, 03/26/2019 - 13:49
Description

This is the full literature discussion based on a communicaiton (J. Am. Chem. Soc. 2011133, 9278). This paper describes a redox-switch yttrium catalyst that is an active catalyst for the polymerization of L-lactide in the reduced form and inactive in the oxidized form. The catalyst contains a ferrocene-based ligand that serves as the redox active site in the catalyst. This full literature discussion is an extension of the one figure literature discussion that is listed below.

1FLO: Redox-switch polymerization catalysis

Submitted by Chip Nataro / Lafayette College on Fri, 03/22/2019 - 16:11
Description

This is what I hope will be a new classification of learning object called a one figure learning object (1FLO). The purpose is to take a single figure from a paper and present students with a series of questions related to interpreting the figure. This literature discussion is based on a paper (J. Am. Chem. Soc. 2011, 133, 9278) from Paula Diaconescu's lab in which a yttrium polymerization catalyst with a ferrocene-based ligand can effectively be rendered active or inactive depeneding on the valence state of the ligand.

Supramolecular Chemistry Videos

Submitted by Shirley Lin / United States Naval Academy on Sun, 03/03/2019 - 08:08
Description

The Rebek Laboratory homepage contains information on and molecular visualizations of a variety of host-guest systems developed by the research group over several decades. The theme behind this set of examples is the use of hydrogen-bonding to achieve self-assembly. Under the "Research" tab, one can find four videos with narration: an introduction to molecular assembly and three videos of specific examples of self-assembled host systems (the cavitand, the cylinder and the volleyball).

Inorganic Chemistry

Submitted by John Lee / University of Tennessee Chattanooga on Wed, 02/13/2019 - 14:25
Description

Catalog Description:  Concepts and models in inorganic chemistry with emphasis on atomic structure and bonding, molecular orbital theory, material science, and descriptive inorganic chemistry including biological and environmental applications.

Advanced ChemDraw (2019 Community Challenge #2)

Submitted by Chantal Stieber / Cal Poly Pomona on Tue, 02/12/2019 - 12:12
Description

This in-class activity was designed for a Chemical Communications course with second-year students. It is the second part of a two-week segment in which students learn how to use ChemDraw (or similar drawing software to create digital drawings of molecules).

More Electron Counting and CBC Assignments for Organometallic Complexes

Submitted by Matt Whited / Carleton College on Thu, 01/31/2019 - 14:55
Description

This in-class group activity extends my original post by providing more examples of varying difficulty for students to assign MLXZ classifications and electron counts to organometallic complexes.  The answers to these are unambiguous within the CBC system, but they provide excellent starting points for conversation with students about bonding formalisms with organometallics.

5-ish Slides About Bridging Hydrides and the [Cr(CO)5HCr(CO)5] anion

Submitted by Kyle Grice / DePaul University on Thu, 01/31/2019 - 13:52
Description

This set of slides was made for my Organometallics class based on questions about bridging hydrides and specifically the chromium molecule. I decided to make these slides to answer the questions, and do a DFT calc to show the MO's involved in bonding of the hydride.