This literature discussion will guide students through an article that applies spectroscopic, structural, and computational analyses to a family of compounds of the type [Re(CO)3(dippM)Br]n+ (dippM = 1,1’-bis(diisopropyl)phosphino metallocene, M = Fe, n= 0 or 1; M = Co, n = 1).
This LO was created to celebrate Dr. Vivian W.-W. Yam's 2022 ACS Award, the Josef Michl Award in Photochemistry. These questions are written to help guide class discussion about this paper and the complexes in it. This LO would be good for an organometallics class or similar upper-division inorganic chemistry class.
This literature discussion focuses on the synthesis, characterization, and polymerization behavior of non-cyclopentadienyl-based Group 4 catalysts for the polymerization of ethylene/1-octene and propylene.
This LO is part of a special VIPEr collection honoring the 2022 ACS National Award recipients in the field of inorganic chemistry. Jerzy Klosin was the recipient of the ACS Award in Industrial Chemistry for the development of versatile homogeneous catalysts for the production of a wide range of polymer-based materials on a large industrial scale.
The literature discussion is based on a manuscript by Gunnoe and coworkers (ACS Catal. 2021, 11, 5688-5702. DOI: 10.1021/acscatal.1c01203). The paper presents mechanistic studies of catalytic oxidative conversion of arenes and olefins to alkenyl arenes with a focus on styrene production.
This LO discuss various aspects of a reversible hydrogen activation by a metal-free phosphonium-borate compound. Attentions are paid to the specific and usual reaction between highly steric phosphine and borane reactants to form a zwitterionic phosphonium borate product. NMR spectroscopy, kinetics and thermodynamics of the hydrogen activation with the phosphonium borate product are also discussed. The original work was published in Science by Douglas W. Stephan and co-workers.
This spreadsheet uses the Eyring equation to draw a connection between activation barriers and the timescale of a reaction. Students input a free energy of activation and can quickly see how long a reaction will take at varying temperatures. This has been particularly useful in computational sections of literature articles that investigate possible mechanistic pathways.
This collection accompanies the IONiC VIPEr nanoCHAt video series NeWBiEs, recorded in Spring 2022. This series is comprised of weekly conversations with two IONiC members, Wes Farrell and Shirley Lin from the US Naval Academy, as they taught a foundation-level inorganic chemistry course for the first time. The LOs discussed in the videos are included in this collection.
Syllabus: https://www.luther.edu/mertzecl/courses/chem372/
Chemistry 372 is a course including molecular and solid-state bonding and structure, molecular symmetry, and coordination and organometallic chemistry.
The course is currently designed for a student population impacted by COVID and College policies that the department offer this course every third semester. This semester I have a diverse student population in terms of developmental levels including cohort year (freshman, junior, senior), prior foundational course work (biochemistry, analytical, physical), and research experience. I have altered the assessment part of the course substantively from prior iterations and reduced topic coverage to provide flexibility.
Course catalog description: The chemistry of non-metals. This course consists of a systematic study of the properties and reactions of the elements and their compounds based upon modern theories of the chemical bond, as well as from the viewpoint of atomic structure and the periodic law.