A DFT Study of Metal Pentacarbonyls

Submitted by Sibrina Collins / College of Arts and Sciences at Lawrence Technological University on Thu, 05/09/2013 - 16:57
Description

Metal carbonyls are the most widely studied organometallic complexes.  This exercise uses Gaussian with the GaussView interface to investigate the role of the metal centers on backbonding to the CO ligand. Density Functional Theory (DFT) methods were used to evaluate two classic metal pentacarbonyls, namely Fe(CO)5 and Ru(CO)5.

 

Inorganic Chemistry Forums

Submitted by Adam Johnson / Harvey Mudd College on Fri, 04/26/2013 - 12:55
Description

Beginning with Volume 43, Issue 25, Inorganic Chemistry began publishing Forums.

Inorganic Chemistry Forums consist of a set of thematically linked papers from leading scientists on a multidisciplinary topic of growing interest. Papers present overviews, research perspectives and original research reports on the Forum theme and are highlighted on the cover of the journal issue in which they appear.

General Chemistry Electronic Study Aids

Submitted by David Kreller / Georgia Southern University on Sun, 04/21/2013 - 13:14
Description

At this website students can access interactive game-like learning resources that cover a wide range of topics in general chemistry.  These learning activities, which are in the form of flash cards, quizzes and matching games, will help student learn and review/drill important general chemistry topics. 

MO Theory for Organometallic Compounds: Pentalene

Submitted by Zachary Tonzetich / University of Texas at San Antonio on Thu, 04/11/2013 - 16:54
Description

This is an in-class exercise for upper level inorganic students designed to highlight aspects of symmetry, group theory, MO theory, and Hückel theory. The exercise is an expansion of a Problem Set question I give to my Advanced Inorganic Chemistry class. In this activity, students will develop the MO diagram for the π system of the pentalene dianion using the Hückel approach. They will then consider the effect of folding the ring system using a Walsh diagram.

The Guided Tour of Metalloproteins

Submitted by Anthony L. Fernandez / Merrimack College on Tue, 04/09/2013 - 07:41
Description

Bob Morris of the University of Toronto created this website when he was teaching a class on Bioinorganic Chemistry.

Online Courses Directory

Submitted by Adam Johnson / Harvey Mudd College on Mon, 04/01/2013 - 07:41
Description

This website is a free and comprehensive resource that is a collection of open college courses that spans videos, audio lectures, and notes given by professors at a variety of universities. The website is designed to be friendly and designed to be easily accessed on any mobile device.

Energy Content and Properties of Fuels

Submitted by Matt Whited / Carleton College on Thu, 03/07/2013 - 10:59
Description

This is a group activity I developed for my "Introduction to Chemistry" class, which is set up primarily to cover the topics we consider to be prerequisites for the first course in our chemistry sequence at Carleton.  However, it covers aspects of thermodynamics (e.g., particularly Hess's Law) that are core topics for most intro courses.

Computational Chemistry

Submitted by Lori Watson / Earlham College on Mon, 02/25/2013 - 16:07

My first computational collection

Semi-Quantitative Molecular Orbital Diagrams

Submitted by Gerard Rowe / University of South Carolina Aiken on Thu, 02/14/2013 - 10:25
Description

In this activity, students construct molecular orbital correlation diagrams for several species (H2, He2, HeH), in a semi-quantitative fashion using a ruler and a list of first ionization energies.  All the MO schema are placed on a common energy scale, and the stability of each orbital is reported using "cm from the top of the paper" as the unit of energy.

Voices of Inorganic Chemistry

Submitted by Sibrina Collins / College of Arts and Sciences at Lawrence Technological University on Sun, 01/27/2013 - 17:08
Description

This learning object focuses on the new video series, “Voices in Inorganic Chemistry,” established to commemorate the 50th anniversary of the American Chemical Society journal, Inorganic Chemistry. The are currently 12 videos celebrating pioneers in the field of inorganic chemistry.  This activity consists of two components, namely the students watching one interview and writing an essay about their chosen inorganic chemist.